%mem=32000MB
%nprocshared=14
#p opt(calcfc,ts,noeigentest) freq b3lyp/TZVP scrf=(smd,solvent=1,4-dioxane) nosymm cphf=conver=7 empiricaldispersion=gd3 int=(acc2e=11,grid=ultrafine)

Title

0 1
 Cu                 3.83647985   -0.13238730    5.96978173
 N                  5.20725485    1.39232470    8.00360973
 N                  5.27751585   -0.71549630    8.42898373
 C                  3.32909885   -1.92427230   10.18941373
 H                  3.93535785   -1.05635730   10.46995373
 C                  4.74477885    0.19114870    7.56551973
 C                  6.02227285    1.24188470    9.11825373
 H                  6.48123085    2.08577270    9.60880773
 C                  6.07019685   -0.09067030    9.38473973
 H                  6.57806185   -0.64716030   10.15676873
 C                  5.04863985   -2.13420430    8.30271973
 C                  4.10435585   -2.73674330    9.15719073
 C                  3.03526585   -2.70169130   11.48152473
 H                  2.59636985   -2.02950830   12.22786173
 H                  3.94680385   -3.13502430   11.90924273
 H                  2.31767885   -3.51406730   11.31938873
 C                  3.84770885   -4.09928030    8.96873773
 H                  3.11804785   -4.60067430    9.59552673
 C                  4.50412885   -4.82258230    7.97354973
 H                  4.28266885   -5.87780930    7.83898473
 C                  5.43674985   -4.19976130    7.14989273
 H                  5.94233985   -4.77559130    6.38078173
 C                  5.73181785   -2.83740030    7.29315173
 C                  6.77070785   -2.18589630    6.38657873
 H                  6.78240585   -1.11076430    6.58782273
 C                  6.42563485   -2.36086830    4.89683573
 H                  6.45101285   -3.41460830    4.59613973
 H                  7.15122885   -1.82205730    4.27624473
 H                  5.42856285   -1.97215430    4.66291873
 C                  8.17794885   -2.72767030    6.69806173
 H                  8.24312585   -3.80423130    6.50032073
 H                  8.44511585   -2.56381530    7.74882573
 H                  8.92824785   -2.22661930    6.07456873
 C                  4.90166985    2.62922070    7.32617973
 C                  5.71941185    3.02228270    6.25135673
 C                  5.36173285    4.19091170    5.56802973
 H                  5.96125085    4.51974170    4.72458273
 C                  4.23635785    4.92220070    5.93930373
 H                  3.96962085    5.81968070    5.38797973
 C                  3.43983385    4.49972570    7.00181773
 H                  2.55284885    5.06818870    7.26330373
 C                  3.75282785    3.33930370    7.71926473
 C                  2.83008285    2.82823270    8.81883873
 H                  3.36976285    2.06875570    9.39459373
 C                  2.40953085    3.92955070    9.80501573
 H                  3.28060985    4.43531170   10.23791273
 H                  1.82584085    3.49548370   10.62521873
 H                  1.78223485    4.69063770    9.32730673
 C                  1.60163185    2.14371070    8.18919673
 H                  1.01777985    2.85703170    7.59572773
 H                  0.94740785    1.72719670    8.96434373
 H                  1.90303585    1.32888370    7.52330073
 C                  6.91920385    2.20222270    5.79292273
 H                  7.05892785    1.37414870    6.49519973
 C                  8.21587385    3.03036370    5.80199773
 H                  8.17424985    3.85496970    5.08100373
 H                  9.07100785    2.39910470    5.53220473
 H                  8.40958485    3.45988270    6.79186473
 C                  6.66327485    1.58795770    4.40348073
 H                  5.76212885    0.96525970    4.39714673
 H                  7.51188485    0.96261370    4.10074973
 H                  6.52976485    2.36554270    3.64230073
 C                  2.02762185   -1.38950730    9.56225573
 H                  2.23201885   -0.79607230    8.66678273
 H                  1.48573885   -0.75777530   10.27689173
 H                  1.37025285   -2.21683330    9.27281773
 F                  3.03560208   -1.91608068    5.20360111
 B                  2.71360078   -1.67902613    3.77863785
 C                  3.96507432   -2.28851513    2.94398819
 C                  1.44753121   -2.64553829    3.47883423
 C                  2.66890831    0.23311586    4.20182129
 H                  4.89031391   -1.71098516    3.10995632
 C                  4.27401784   -3.73250593    3.40735617
 C                  3.62825454   -2.16204903    1.43799153
 C                  1.75810654   -4.08287040    3.96562565
 H                  0.54266884   -2.32010082    4.01985681
 C                  1.11504906   -2.55348617    1.96763927
 C                  1.66027516    0.91513635    5.15439068
 C                  3.58510880    1.31242887    3.58729044
 H                  2.08369041   -0.18927742    3.36578767
 H                  4.67881361   -3.67500491    4.42844032
 H                  5.07924528   -4.17716395    2.79902096
 C                  3.06772879   -4.69718396    3.42086111
 C                  2.29997747   -2.82737040    1.01326477
 H                  4.44223762   -2.57149399    0.81643567
 H                  3.57232192   -1.09089937    1.19254719
 H                  0.92580305   -4.76616959    3.72713532
 H                  1.82138290   -4.05269987    5.06178689
 H                  0.73754059   -1.54041611    1.76646909
 H                  0.28942453   -3.23634313    1.70705098
 C                  0.87733858    2.06201467    4.49577978
 H                  2.20850622    1.32361168    6.01744111
 H                  0.96340494    0.17127059    5.56280744
 C                  2.81464160    2.46409815    2.92373942
 H                  4.21950806    1.74090600    4.38302591
 H                  4.27620114    0.86545255    2.86149022
 H                  3.32625871   -5.58306717    4.02088965
 H                  2.89565121   -5.07692584    2.40808898
 H                  2.03352726   -2.48555485    0.00213512
 H                  2.45182319   -3.90771177    0.92163540
 C                  1.82817690    3.11308201    3.90407072
 H                  0.19847677    2.53216467    5.22216517
 H                  0.24500576    1.65674120    3.69088561
 H                  3.51130587    3.21540870    2.52480943
 H                  2.25568704    2.06857713    2.06164340
 H                  1.26117118    3.91382992    3.40855414
 H                  2.39204912    3.58660145    4.72301130




