%mem=15000MB
%nprocshared=6
#p opt freq b3lyp/TZVP scrf=(smd,solvent=1,4-dioxane) nosymm cphf=conver=7 empiricaldispersion=gd3 int=(acc2e=11,grid=ultrafine)

Title Card Required

0 1
 C                 -1.49764149   -0.02948113    0.00000000
 C                 -0.82236718    1.14549616    0.00000000
 H                 -1.35920133    2.07108197    0.00000000
 H                  0.24763072    1.14761528    0.00000000
 H                 -2.56764149   -0.02948113    0.00000000
 S                 -0.61069619   -1.57276595    0.00000000
 C                 -0.69776420   -2.30714620    1.61910618
 F                 -1.98915404   -2.53031434    1.94315595
 F                 -0.14510373   -1.47048959    2.52302660
 F                 -0.02506954   -3.47760846    1.61910977


