%mem=15000MB
%nprocshared=6
#p opt freq b3lyp/TZVP scrf=(smd,solvent=1,4-dioxane) nosymm cphf=conver=7 empiricaldispersion=gd3 int=(acc2e=11,grid=ultrafine)

Title Card Required

0 1
 C                 -1.26179189    0.31493946   -0.00140548
 H                 -0.90513729   -0.69386859   -0.00336150
 H                 -0.90511885    0.82103082   -0.87407716
 C                 -0.74845022    1.03845627    1.25740497
 H                 -1.44905721    1.79432384    1.54500549
 H                 -0.63787029    0.33289185    2.05418030
 S                 -3.04179189    0.31496107   -0.00140602
 C                 -3.63514517   -1.33480322   -0.30899288
 F                 -3.18556645   -1.75820462   -1.50945538
 F                 -3.18473910   -2.16255042    0.65768647
 F                 -4.98514507   -1.33488034   -0.30849187
 B                  0.71141355    1.73608259    0.93396208
 C                  2.07028425    1.09849659    1.36242014
 C                  0.85438641    3.09141801    0.17272498
 H                  1.94764186    0.14946285    1.89317306
 C                  2.86815522    0.82262739    0.05471049
 C                  2.75042347    2.11023817    2.33052396
 C                  1.66251136    2.79169584   -1.12325326
 H                 -0.10918911    3.52053327   -0.11847222
 C                  1.54946286    4.08236285    1.15127117
 H                  2.37570975   -0.00633262   -0.46648487
 H                  3.87300738    0.46623140    0.30707313
 C                  2.97842722    2.01789537   -0.91211384
 C                  2.84037067    3.55830727    1.81016039
 H                  3.75434802    1.75364370    2.58610288
 H                  2.18120980    2.10796440    3.26723456
 H                  1.87298406    3.72973031   -1.64860630
 H                  1.01622217    2.21021179   -1.79071297
 H                  0.82903927    4.33038076    1.93906404
 H                  1.76356677    5.02224074    0.63056826
 H                  3.32924648    1.65255998   -1.88215668
 H                  3.75177389    2.70043777   -0.56235506
 H                  3.09829491    4.21536347    2.64633562
 H                  3.66896441    3.64349963    1.10844518


