%mem=15000MB
%nprocshared=7
#p opt freq b3lyp/TZVP scrf=(smd,solvent=1,4-dioxane) nosymm cphf=conver=7 empiricaldispersion=gd3 int=(acc2e=11,grid=ultrafine)

Title Card Required

0 1
 C                 -1.08310793   -0.40340529   -0.55875287
 H                 -0.43679755   -0.94354750   -1.21862352
 H                 -2.14380879   -0.52391374   -0.63149482
 C                 -0.55826492    0.43333570    0.36913256
 H                 -1.20457536    0.97347906    1.02900221
 C                  0.96835142    0.60677515    0.47382887
 H                  1.28963828    0.34950782    1.46149698
 H                  1.44953706   -0.03333379   -0.23583368
 C                  1.34000735    2.07176546    0.17840504
 F                  0.93464544    2.39635508   -1.06771827
 F                  0.73290398    2.87937953    1.07377368
 F                  2.67827492    2.22380654    0.27018428

