%mem=15000MB
%nprocshared=7
#p opt freq b3lyp/TZVP scrf=(smd,solvent=1,4-dioxane) nosymm cphf=conver=7 empiricaldispersion=gd3 int=(acc2e=11,grid=ultrafine)

Title Card Required

0 1
 C                  0.85443300    0.61252500    0.00724000
 H                  1.35359600   -0.33130200    0.22577800
 H                  1.00744700    0.86357000   -1.04232900
 C                 -0.63288600    0.53109800    0.33532400
 H                 -1.10605500    1.49756600    0.14041400
 H                 -0.76393400    0.32800400    1.40212900
 C                 -1.33135700   -0.55917100   -0.48379100
 H                 -1.19757100   -0.36855000   -1.56018700
 H                 -0.83364300   -1.52842800   -0.33152900
 B                 -2.86921900   -0.77865100   -0.25767700
 C                 -3.66529700   -1.91459700   -0.99958100
 C                 -3.80800400    0.04978500    0.69324600
 H                 -3.03083900   -2.50503300   -1.67073500
 C                 -4.21447000   -2.88253500    0.08628200
 C                 -4.75755500   -1.23615700   -1.87152500
 C                 -4.35060200   -0.93217600    1.77101400
 H                 -3.28855700    0.85426500    1.22343800
 C                 -4.90548600    0.71310600   -0.18600500
 H                 -3.35904100   -3.41195500    0.52325700
 H                 -4.83396100   -3.65365400   -0.38588900
 C                 -5.00703700   -2.21145900    1.22240000
 C                 -5.66429600   -0.24180700   -1.12495400
 H                 -5.37503800   -2.00268500   -2.35365900
 H                 -4.25087400   -0.70389600   -2.68590700
 H                 -5.05951300   -0.40692300    2.42123700
 H                 -3.51001400   -1.21868800    2.41467900
 H                 -4.42136500    1.48754200   -0.79307200
 H                 -5.62119900    1.23968800    0.45562300
 H                 -5.12570100   -2.92711100    2.04195300
 H                 -6.01770000   -1.98774700    0.88315000
 H                 -6.21902300    0.35141900   -1.85868700
 H                 -6.42013000   -0.78743000   -0.56122800
 C                  1.51569293    1.70892270    0.86295455
 F                  1.37171165    1.40703415    2.17086613
 F                  0.92583741    2.89607978    0.60755576
 F                  2.82920566    1.78478202    0.56058114

