%mem=16GB
%nprocshared=12
#p opt freq b3lyp/gen pseudo=cards scrf=(smd,solvent=1,4-dioxane) nosymm cphf=conver=7 empiricaldispersion=gd3 int=(acc2e=11,grid=ultrafine)

Title

0 1
 O                  2.17712000   -0.14409400    1.93850600
 C                  1.26460000   -0.65058700    2.63200200
 O                  1.34391700   -1.48054700    3.55975700
 C                 -0.20440900   -0.23732600    2.25374500
 H                 -0.59532700   -1.04638800    1.63376000
 H                 -0.82255600   -0.19703900    3.14998100
 C                 -0.26799300    1.07774600    1.46638900
 H                  0.69414100    1.17666900    0.95348400
 C                 -0.38453800    2.28484600    2.38744100
 C                 -1.34942200    1.06668600    0.39973000
 F                 -1.07183700    0.12967300   -0.53710200
 F                 -2.57969500    0.77384700    0.88571300
 F                 -1.46968300    2.24525300   -0.26068500
 F                 -1.62604400    2.42187000    2.92345000
 F                 -0.11166900    3.45220000    1.75296800
 F                  0.47484600    2.19459300    3.41728600
 Cs                 4.46916440   -1.57696827    3.22071704

C O F H 0
TZVP
****
Cs 0
Def2SVP
P   1   1.00
    0.33986441258E-02      1.0000000
****

CS     0
CS-ECP     3     46
f-ul potential
  1
2      3.1232690            -28.8843090
s-ul potential
  3
2      4.0797500             84.5477300
2      2.4174060             16.6541730
2      3.1232690             28.8843090
p-ul potential
  3
2      5.5140800            157.0490590
2      2.1603160             26.4233070
2      3.1232690             28.8843090
d-ul potential
  3
2      1.8074100             13.1727530
2      0.8581820              3.3428330
2      3.1232690             28.8843090



