%mem=15000MB
%nprocshared=7
#p opt freq b3lyp/TZVP scrf=(smd,solvent=1,4-dioxane) nosymm cphf=conver=7 empiricaldispersion=gd3 int=(acc2e=11,grid=ultrafine)

Title Card Required

0 1
 Cu                 2.83937200   -0.51244700    4.27817300
 N                  4.41714900    1.19161500    6.12639700
 N                  4.96930400   -0.85994200    6.35339800
 C                  3.15627200   -2.48802400    7.91075100
 H                  3.40802300   -1.43731700    8.05983200
 C                  4.13885300   -0.04980400    5.64595300
 C                  5.39603800    1.15590700    7.10960400
 H                  5.74417500    2.04509400    7.60446900
 C                  5.74594600   -0.14279800    7.25319200
 H                  6.46191800   -0.61976400    7.89862800
 C                  5.02508200   -2.28731000    6.18021000
 C                  4.17989900   -3.08863500    6.96005600
 C                  3.16071100   -3.15520600    9.29136900
 H                  2.47084500   -2.63598600    9.96100500
 H                  4.15419800   -3.12982900    9.74524200
 H                  2.84074500   -4.19831900    9.24197800
 C                  4.25170200   -4.46929100    6.77272800
 H                  3.60904700   -5.12149900    7.34991800
 C                  5.12232700   -5.01846100    5.84144500
 H                  5.15997800   -6.09306200    5.70750800
 C                  5.93176400   -4.19808500    5.06813500
 H                  6.58653200   -4.64065300    4.32837900
 C                  5.89869700   -2.81111400    5.21784000
 C                  6.72275700   -1.91586100    4.30553000
 H                  6.68925900   -0.90157500    4.70453100
 C                  6.09469400   -1.87709100    2.90299000
 H                  6.11061300   -2.86785500    2.44194900
 H                  6.64642600   -1.19291000    2.25387400
 H                  5.05461200   -1.54481300    2.94545500
 C                  8.19815400   -2.32946800    4.24357100
 H                  8.32796800   -3.31181700    3.78419900
 H                  8.64661300   -2.36385300    5.23925900
 H                  8.76411500   -1.61301800    3.64318900
 C                  3.76128300    2.38297700    5.65395800
 C                  4.32657700    3.07217500    4.57188600
 C                  3.65480100    4.20427900    4.11036100
 H                  4.05298400    4.75736200    3.26967100
 C                  2.47038100    4.62171600    4.70188800
 H                  1.95984600    5.49946200    4.32376300
 C                  1.92988300    3.91374000    5.76584800
 H                  0.99578100    4.24113500    6.20402200
 C                  2.56347800    2.77552200    6.26604400
 C                  1.92359500    1.96713900    7.38398400
 H                  2.65198200    1.23406100    7.73264400
 C                  1.54014700    2.83287900    8.59077300
 H                  2.39808500    3.39341000    8.96941600
 H                  1.16427300    2.20263100    9.40056700
 H                  0.75374000    3.54976000    8.34475500
 C                  0.71204000    1.18994400    6.84647400
 H                 -0.05985300    1.87203300    6.48166500
 H                  0.27225600    0.57016700    7.63160000
 H                  0.99924800    0.53921900    6.01823200
 C                  5.57740900    2.57074200    3.86699500
 H                  6.06232600    1.84172300    4.51770800
 C                  6.59636000    3.68441700    3.59669000
 H                  6.22372000    4.41177200    2.87214600
 H                  7.51499900    3.25936400    3.18495100
 H                  6.85453800    4.22334300    4.51128900
 C                  5.19294500    1.84285200    2.56908600
 H                  4.50798800    1.01671200    2.76944100
 H                  6.08141400    1.44030200    2.07638300
 H                  4.69798000    2.52411100    1.87270100
 C                  1.75941400   -2.53847700    7.27084800
 H                  1.75148100   -2.03284500    6.30251100
 H                  1.02215900   -2.05350400    7.91520700
 H                  1.44188500   -3.57183400    7.11048100
 C                  1.51922571   -0.87836225    2.90452101
 C                  0.71414616    0.01045586    1.96610568
 H                  0.86464377   -1.29978609    3.63856764
 H                 -0.10269459   -0.54165602    1.50326631
 H                  1.34291432    0.43476944    1.18468664
 S                 -0.02558295    1.41812639    2.92388236
 C                 -0.90916473    2.23579082    1.55970177
 F                 -0.09098643    2.63962786    0.56153711
 F                 -1.84193837    1.44496533    0.98152074
 F                 -1.53968323    3.32621653    2.03284083
 H                  1.97121075   -1.66759741    2.34085675


