%mem=15000MB
%nprocshared=7
#p opt freq b3lyp/TZVP scrf=(smd,solvent=1,4-dioxane) nosymm cphf=conver=7 empiricaldispersion=gd3 int=(acc2e=11,grid=ultrafine)

Title Card Required

0 1
 Cu                 2.90089100   -0.91656000    4.23276600
 N                  4.25579500    1.04125300    5.90409800
 N                  5.03021600   -0.88971600    6.39321300
 C                  3.35019800   -2.50303700    8.10190700
 H                  3.49876800   -1.42319800    8.13897700
 C                  4.14015900   -0.27327200    5.57513600
 C                  5.19525500    1.24033400    6.90428200
 H                  5.42097700    2.21741100    7.29312100
 C                  5.68609000    0.01793900    7.21484100
 H                  6.42739500   -0.29056300    7.93029700
 C                  5.24452600   -2.31244200    6.39884000
 C                  4.45505100   -3.10217500    7.24563300
 C                  3.37542400   -3.01284900    9.54783300
 H                  2.62400400   -2.48889200   10.14344500
 H                  4.35028700   -2.84838600   10.01278600
 H                  3.15114600   -4.08003700    9.60869200
 C                  4.66857000   -4.48081400    7.21942100
 H                  4.07278100   -5.12653500    7.85143500
 C                  5.62219800   -5.03870500    6.37904500
 H                  5.77003400   -6.11210000    6.37013000
 C                  6.37838400   -4.23168400    5.53996900
 H                  7.10194800   -4.68592200    4.87541700
 C                  6.20434400   -2.84729100    5.52919900
 C                  6.97279600   -1.97434000    4.54934000
 H                  6.85649800   -0.93498100    4.85878300
 C                  6.36377100   -2.10390800    3.14374400
 H                  6.46323200   -3.12605600    2.76952300
 H                  6.86849400   -1.43562700    2.44190900
 H                  5.30060900   -1.85200200    3.14961000
 C                  8.47627700   -2.27557500    4.53531500
 H                  8.68936800   -3.27601900    4.15281000
 H                  8.90883300   -2.19899500    5.53555000
 H                  8.99461000   -1.56391100    3.88815800
 C                  3.47137700    2.06856400    5.26886300
 C                  3.96697800    2.66169300    4.09956400
 C                  3.16564800    3.61707800    3.47391600
 H                  3.50782800    4.08581500    2.56016400
 C                  1.92297600    3.95584600    3.99055100
 H                  1.31000100    4.69056300    3.48251600
 C                  1.45264900    3.34210200    5.14284200
 H                  0.47056500    3.59819300    5.51957000
 C                  2.21494000    2.38020100    5.80630100
 C                  1.64940400    1.65610900    7.01802100
 H                  2.43617000    1.02758100    7.43584100
 C                  1.20816900    2.62637900    8.12140500
 H                  2.02735200    3.28168000    8.42665100
 H                  0.87373800    2.07164000    9.00151900
 H                  0.37818000    3.25833500    7.79778800
 C                  0.50003200    0.72723600    6.59560400
 H                 -0.33538700    1.29815400    6.18331900
 H                  0.12955800    0.16177800    7.45408000
 H                  0.82863700    0.01540000    5.83503300
 C                  5.28365200    2.23309000    3.47185600
 H                  5.79826500    1.57841200    4.17568200
 C                  6.21374700    3.42020900    3.19181900
 H                  5.79996000    4.09253900    2.43694100
 H                  7.17761300    3.06435300    2.81933900
 H                  6.39614400    4.00534500    4.09626100
 C                  5.01994700    1.41557500    2.19747600
 H                  4.39101000    0.54781600    2.40983900
 H                  5.95985900    1.05921700    1.76912800
 H                  4.51405300    2.02094900    1.44146900
 C                  1.98300400   -2.75476200    7.44568000
 H                  1.95521700   -2.36280100    6.42626100
 H                  1.18684600   -2.27275000    8.01817800
 H                  1.76553500   -3.82491500    7.39883400
 C                  1.52401500   -1.19650200    2.85213500
 C                  0.96531300    0.17778400    2.44820800
 H                  0.70240800   -1.82798300    3.22076600
 H                  1.76753300    0.80403300    2.04615900
 H                  0.58751400    0.70443400    3.32980500
 H                  1.91478500   -1.70775000    1.96079800
 C                 -0.15588300    0.07815200    1.41400200
 H                  0.19854500   -0.38437800    0.49328700
 H                 -0.99729400   -0.49240000    1.80633700
 C                 -0.66741337    1.48899678    1.06838129
 F                  0.35675185    2.23895574    0.60887378
 F                 -1.62251322    1.40116667    0.11834436
 F                 -1.18489809    2.06364691    2.17494661

