%mem=15000MB
%nprocshared=7
#p opt freq b3lyp/TZVP scrf=(smd,solvent=1,4-dioxane) nosymm cphf=conver=7 empiricaldispersion=gd3 int=(acc2e=11,grid=ultrafine)

Title Card Required

0 1
 Cu                 2.86620700   -0.77053100    4.19900800
 N                  4.24804700    1.11709700    5.95471600
 N                  4.96572400   -0.85401300    6.36516400
 C                  3.30433500   -2.50462500    8.05281900
 H                  3.54793800   -1.45182100    8.20252600
 C                  4.09250200   -0.17861700    5.57611000
 C                  5.19805900    1.24802800    6.95689900
 H                  5.45488800    2.20173700    7.38261800
 C                  5.65362800    0.00010500    7.21674200
 H                  6.38904100   -0.35784900    7.91514300
 C                  5.13599700   -2.28078800    6.28722100
 C                  4.33639200   -3.09374400    7.10312400
 C                  3.31749500   -3.17061000    9.43409500
 H                  2.63371400   -2.64784000   10.10706000
 H                  4.31383900   -3.14805600    9.88165000
 H                  2.99226500   -4.21218400    9.38887000
 C                  4.47162600   -4.47437700    6.95848200
 H                  3.86037000   -5.13779800    7.55595200
 C                  5.36225200   -5.01153000    6.03817000
 H                  5.44403100   -6.08690700    5.93327800
 C                  6.14404300   -4.18016600    5.24809200
 H                  6.82354900   -4.61497900    4.52660900
 C                  6.04871900   -2.79204700    5.35503600
 C                  6.86589500   -1.88714400    4.44570600
 H                  6.77302000   -0.86505100    4.81442200
 C                  6.30473400   -1.91002300    3.01580000
 H                  6.38501100   -2.90744300    2.57867400
 H                  6.85752800   -1.21490400    2.37917300
 H                  5.25129300   -1.62502000    2.99913600
 C                  8.35890100   -2.23988300    4.46292300
 H                  8.54803000   -3.22718000    4.03593000
 H                  8.76014000   -2.23073500    5.47903600
 H                  8.92302000   -1.51558800    3.87031600
 C                  3.50220500    2.19535600    5.35818700
 C                  4.02117900    2.81367000    4.21234600
 C                  3.26482100    3.83330200    3.63380000
 H                  3.62731700    4.32573500    2.74059900
 C                  2.04130800    4.20747200    4.17100300
 H                  1.46467000    4.99519700    3.70121500
 C                  1.54278400    3.56235500    5.29392300
 H                  0.57417200    3.84664000    5.68484200
 C                  2.25949100    2.53576600    5.90981500
 C                  1.65611100    1.77296200    7.07836100
 H                  2.41900900    1.10538800    7.47983300
 C                  1.21603100    2.69977600    8.21863200
 H                  2.04127300    3.32733100    8.56326400
 H                  0.86159000    2.11109300    9.06827400
 H                  0.39931400    3.35825200    7.91474700
 C                  0.49280500    0.89522700    6.58967100
 H                 -0.31928800    1.50742100    6.19015700
 H                  0.09170700    0.29730300    7.41141700
 H                  0.81839600    0.21326000    5.80066900
 C                  5.31222700    2.35077400    3.55639800
 H                  5.79631100    1.63668000    4.22326900
 C                  6.29948200    3.50265100    3.32915900
 H                  5.91618300    4.23065500    2.61070800
 H                  7.24293600    3.11848300    2.93346200
 H                  6.51410300    4.03258100    4.26017500
 C                  5.00095000    1.61241600    2.24461900
 H                  4.33039200    0.76729700    2.41739700
 H                  5.91876700    1.23079500    1.79132100
 H                  4.52136100    2.27894500    1.52372600
 C                  1.90437500   -2.56607800    7.42186000
 H                  1.88187500   -2.06017700    6.45524200
 H                  1.17019500   -2.08794900    8.07498400
 H                  1.59445500   -3.60053700    7.26033200
 C                  1.54122300   -1.08435800    2.77726300
 H                  0.74238300   -1.76885100    3.09605000
 H                  1.99448600   -1.54425900    1.88766600
 C                  2.87111100   -4.16014300    3.61806800
 O                  3.67161700   -4.04955600    2.78526900
 O                  2.06684300   -4.31329000    4.44035800
 C                  0.92081900    0.26688300    2.38402000
 H                  1.70384900    0.96105500    2.06391500
 H                  0.44540200    0.72859900    3.25499700
 C                 -0.11117800    0.13222900    1.26416300
 H                  0.34678900   -0.26748300    0.35979900
 H                 -0.93588300   -0.51169400    1.56817500
 C                 -0.69297419    1.51704211    0.92444864
 F                 -1.61360098    1.39046821   -0.05479871
 F                  0.29910623    2.33181800    0.50681642
 F                 -1.27444380    2.04279911    2.02352673

