%mem=15000MB
%nprocshared=8
#p opt freq b3lyp/TZVP scrf=(smd,solvent=1,4-dioxane) nosymm cphf=conver=7 empiricaldispersion=gd3 int=(acc2e=11,grid=ultrafine)

Title Card Required

0 1
 Cu                 2.79208800   -0.24040200    4.17735500
 N                  4.43872900    1.26075600    6.21333200
 N                  4.85356500   -0.83528800    6.16985500
 C                  2.87505300   -2.51555300    7.46793700
 H                  3.15793900   -1.49068800    7.70878400
 C                  4.07315400    0.11318400    5.58783300
 C                  5.42689300    1.03607100    7.16229500
 H                  5.84062300    1.83086700    7.75719800
 C                  5.68800000   -0.29164300    7.13548300
 H                  6.37796900   -0.89242800    7.70094400
 C                  4.79509600   -2.22630300    5.80043700
 C                  3.85920300   -3.05080000    6.43996300
 C                  2.90301600   -3.31389100    8.77752900
 H                  2.23575800   -2.85611700    9.51199600
 H                  3.90759700   -3.34303400    9.20593600
 H                  2.57170200   -4.34450000    8.63244300
 C                  3.80423900   -4.38773100    6.04421500
 H                  3.08810700   -5.05310700    6.50940900
 C                  4.63759700   -4.87188500    5.04604500
 H                  4.57411000   -5.91150300    4.74773500
 C                  5.53838900   -4.02607200    4.41434600
 H                  6.16285400   -4.41170400    3.61877500
 C                  5.63455600   -2.68168600    4.77439100
 C                  6.56084800   -1.74732100    4.01223600
 H                  6.59124900   -0.79294300    4.53850500
 C                  5.99634000   -1.47698100    2.60841800
 H                  5.94823100   -2.39789500    2.02212800
 H                  6.62857200   -0.76698100    2.06993400
 H                  4.98745600   -1.06101800    2.66323100
 C                  8.00052100   -2.27256100    3.94473900
 H                  8.07071900   -3.19685700    3.36685900
 H                  8.39966200   -2.47006900    4.94238900
 H                  8.64742700   -1.53592100    3.46204100
 C                  3.84476700    2.53563600    5.90982200
 C                  4.39523800    3.29905400    4.87210400
 C                  3.76326100    4.50296400    4.55858800
 H                  4.14747800    5.11335200    3.75163300
 C                  2.63310300    4.91618300    5.25003900
 H                  2.15025500    5.84903100    4.98415300
 C                  2.11125300    4.13762200    6.27503000
 H                  1.21997000    4.46798200    6.79214300
 C                  2.70711100    2.92731600    6.62973200
 C                  2.09598500    2.04039900    7.70379700
 H                  2.84241600    1.29973600    7.99369000
 C                  1.71859500    2.81626300    8.97122000
 H                  2.56776900    3.38023100    9.36402200
 H                  1.38494700    2.12322200    9.74728600
 H                  0.90191700    3.51884300    8.79246200
 C                  0.88733400    1.27662800    7.14094000
 H                  0.09395000    1.96619200    6.84555500
 H                  0.48326300    0.59478000    7.89335900
 H                  1.16101200    0.69157500    6.26132900
 C                  5.59155600    2.81992500    4.06488300
 H                  6.02104100    1.95784700    4.57639700
 C                  6.69263300    3.88371400    3.96675200
 H                  6.36223700    4.75947500    3.40387700
 H                  7.56527800    3.47497700    3.45142700
 H                  7.01124600    4.22183700    4.95566600
 C                  5.14540600    2.35013500    2.67178400
 H                  4.38896200    1.56616600    2.74049400
 H                  5.99747600    1.95610200    2.11256500
 H                  4.71633200    3.17489200    2.09921900
 C                  1.46025900   -2.47150000    6.86879300
 H                  1.43694000   -1.86924900    5.95732100
 H                  0.75423600   -2.03744400    7.58045100
 H                  1.11032000   -3.47550900    6.61681800
 C                  1.58057200   -0.84804000    2.75424600
 H                  0.52729200   -0.61595200    2.96524600
 H                  1.79688300   -0.36900100    1.78936900
 C                  1.71625700   -2.38206000    2.57905600
 H                  2.75560300   -2.63519400    2.35059600
 H                  1.48322900   -2.88247500    3.52329000
 C                  0.82574100   -2.93199500    1.49495600
 C                  1.25611400   -2.97540900    0.16411900
 C                 -0.48055800   -3.34670400    1.77479100
 C                  0.41898000   -3.41419600   -0.85119500
 H                  2.26360600   -2.65560700   -0.07720900
 C                 -1.32909100   -3.78853200    0.76936100
 H                 -0.83725100   -3.31854200    2.79822500
 C                 -0.88106700   -3.81741200   -0.54985100
 H                  0.77062400   -3.43883100   -1.87484500
 H                 -2.33705700   -4.10423400    1.00653600
 C                 -1.76792100   -4.34682300   -1.63333000
 F                 -3.08415400   -4.17041200   -1.36450600
 F                 -1.60230200   -5.68614600   -1.83294900
 F                 -1.53112000   -3.76147700   -2.83300200


