%mem=13000MB
%nprocshared=6
#p opt freq b3lyp/TZVP scrf=(smd,solvent=1,4-dioxane) nosymm cphf=conver=7 empiricaldispersion=gd3 int=(acc2e=11,grid=ultrafine)

Title Card Required

0 1
 Cu                 2.75913400   -0.23969600    4.19061500
 N                  4.43693000    1.26809600    6.20752200
 N                  4.83794900   -0.83017100    6.15771000
 C                  2.88244000   -2.49691800    7.50113400
 H                  3.18941400   -1.47997200    7.74661900
 C                  4.05414300    0.12331400    5.58642300
 C                  5.43678300    1.03591700    7.14287800
 H                  5.86373500    1.82797000    7.73204500
 C                  5.68949000   -0.29289300    7.11152400
 H                  6.38364600   -0.89855600    7.66656500
 C                  4.76649000   -2.22130500    5.79235300
 C                  3.83886700   -3.03982300    6.45119900
 C                  2.91813900   -3.30792800    8.80268900
 H                  2.27552900   -2.84232000    9.55402500
 H                  3.92993700   -3.36307300    9.21114900
 H                  2.56111900   -4.32960100    8.65550000
 C                  3.76741000   -4.37634900    6.05711100
 H                  3.05558000   -5.03680300    6.53570600
 C                  4.57980500   -4.86657300    5.04456100
 H                  4.50372200   -5.90578700    4.74777700
 C                  5.47675900   -4.02787900    4.39804600
 H                  6.08623900   -4.41890400    3.59350400
 C                  5.58763100   -2.68372000    4.75486000
 C                  6.51078500   -1.75653600    3.98014300
 H                  6.55368900   -0.80215100    4.50548000
 C                  5.93216700   -1.48260100    2.58280800
 H                  5.87173200   -2.40302100    1.99689100
 H                  6.56320600   -0.77661000    2.03737800
 H                  4.92675600   -1.05990100    2.64976400
 C                  7.94613100   -2.29139600    3.89670900
 H                  8.00388200   -3.21591000    3.31781100
 H                  8.35489700   -2.49184200    4.88987800
 H                  8.59259400   -1.55884000    3.40720800
 C                  3.85766000    2.55520700    5.92799900
 C                  4.41555300    3.33288800    4.90486800
 C                  3.82582500    4.57103100    4.64661900
 H                  4.22137400    5.19740000    3.85742700
 C                  2.72673300    5.00313000    5.37562200
 H                  2.28039000    5.96597200    5.15716900
 C                  2.18641800    4.20328700    6.37364700
 H                  1.31640300    4.54730100    6.91781300
 C                  2.73906200    2.95728300    6.67082900
 C                  2.09421200    2.04401300    7.70176700
 H                  2.80595000    1.25478200    7.94663400
 C                  1.75402500    2.76476600    9.01151500
 H                  2.62997000    3.26355800    9.43272500
 H                  1.38704900    2.04658800    9.74873900
 H                  0.97301100    3.51604900    8.87581300
 C                  0.85291300    1.36792600    7.09694000
 H                  0.09229700    2.11023700    6.84191800
 H                  0.41395100    0.66365200    7.80776400
 H                  1.10540700    0.82105400    6.18561300
 C                  5.56647600    2.82854600    4.04882700
 H                  5.98929300    1.94929700    4.53581100
 C                  6.69698500    3.85553500    3.90941100
 H                  6.37623800    4.74486800    3.36251100
 H                  7.53424500    3.41951500    3.35902300
 H                  7.06668600    4.17798400    4.88561300
 C                  5.04292600    2.38322700    2.67374300
 H                  4.26025100    1.62727700    2.77424600
 H                  5.85145000    1.95932700    2.07327200
 H                  4.62133300    3.22912800    2.12484700
 C                  1.45842500   -2.42018800    6.92806400
 H                  1.43004100   -1.80587500    6.02479200
 H                  0.77271500   -1.98429800    7.65847400
 H                  1.08700200   -3.41480200    6.66927400
 C                  1.55505000   -0.88253800    2.77525900
 C                  1.72064300   -2.41093100    2.58515400
 H                  2.60582740   -2.75548903    3.12715422
 H                  0.88817393   -2.91955124    3.02470001
 H                  1.80729081   -2.70033609    1.55868586
 C                  1.83168680   -0.18963717    1.42805430
 C                  0.07533608   -0.58484794    3.08091785
 F                  1.65004009    1.14146626    1.56097583
 F                  3.10400909   -0.43454400    1.04895454
 F                  0.98351750   -0.66842069    0.49324139
 F                 -0.27318495   -1.18058622    4.24114584
 F                 -0.10234817    0.74904819    3.18885034
 F                 -0.69561047   -1.06204371    2.08070506


