%mem=32000MB
%nprocshared=14
#p opt freq b3lyp/TZVP scrf=(smd,solvent=1,4-dioxane) nosymm cphf=conver=7 empiricaldispersion=gd3 int=(acc2e=11,grid=ultrafine)

Title Card Required

0 1
 Cu                -0.17794100   -0.12993700   -2.71930300
 N                  1.58158800    1.41045100   -0.97580200
 N                  2.00015000   -0.69300300   -0.88447100
 C                  0.21223300   -2.25216700    0.77502300
 H                  0.55530300   -1.22499900    0.93585800
 C                  1.18318600    0.21347900   -1.49167600
 C                  2.61860700    1.25344600   -0.06359400
 H                  3.05950100    2.09470900    0.44775600
 C                  2.88547100   -0.07695900   -0.00837400
 H                  3.60866900   -0.63964500    0.56084800
 C                  1.92718400   -2.11143300   -1.12327100
 C                  1.08452200   -2.88347300   -0.30324800
 C                  0.31670100   -2.98139000    2.12435600
 H                 -0.26047200   -2.44589400    2.88761400
 H                  1.35624800   -3.04459800    2.46708000
 H                 -0.08172300   -4.00117600    2.07104800
 C                  1.01949300   -4.25738300   -0.56299500
 H                  0.37265200   -4.88618700    0.04108400
 C                  1.75918000   -4.82649000   -1.59785100
 H                  1.69187300   -5.89481200   -1.78594900
 C                  2.57143300   -4.03164500   -2.40349200
 H                  3.12312500   -4.48547200   -3.22137800
 C                  2.67130200   -2.65193600   -2.18659700
 C                  3.49944100   -1.77930300   -3.12131100
 H                  3.54263700   -0.76978500   -2.70071900
 C                  2.81125500   -1.67538700   -4.49562000
 H                  2.75596500   -2.65652200   -4.98262300
 H                  3.36907300   -1.00024000   -5.15566000
 H                  1.78826800   -1.29328300   -4.39900700
 C                  4.94800900   -2.27648500   -3.25771500
 H                  4.99861600   -3.26659400   -3.72540600
 H                  5.44290300   -2.34210500   -2.28143100
 H                  5.52630500   -1.58821200   -3.88565900
 C                  0.97544600    2.66799300   -1.33062200
 C                  1.55677000    3.42225200   -2.36730900
 C                  0.93275500    4.62687800   -2.71015600
 H                  1.34258200    5.23526300   -3.50995000
 C                 -0.21867500    5.05134900   -2.04835000
 H                 -0.69064600    5.98772500   -2.33392800
 C                 -0.77267600    4.27896800   -1.03094700
 H                 -1.67772300    4.61505700   -0.53370300
 C                 -0.18662700    3.06594100   -0.64748900
 C                 -0.82897800    2.20806200    0.43590500
 H                 -0.16447700    1.36445600    0.64733200
 C                 -1.01175000    2.98263600    1.75231000
 H                 -0.05975500    3.39018800    2.11261700
 H                 -1.41268000    2.31963600    2.52838900
 H                 -1.71278800    3.81795800    1.63997900
 C                 -2.16552000    1.62587200   -0.06061700
 H                 -2.88816600    2.42321900   -0.27251700
 H                 -2.60354200    0.96546300    0.69738800
 H                 -2.02827000    1.04711800   -0.98121500
 C                  2.76807200    2.91194000   -3.13965300
 H                  3.28510900    2.17679200   -2.51349700
 C                  3.78454000    4.01630100   -3.47004300
 H                  3.38535400    4.74224000   -4.18776200
 H                  4.68079900    3.57578000   -3.92245600
 H                  4.09244900    4.56421600   -2.57179900
 C                  2.30904500    2.18468500   -4.41902200
 H                  1.61461800    1.36980900   -4.18762400
 H                  3.16960300    1.76302700   -4.95287800
 H                  1.79443600    2.87797900   -5.09549900
 C                 -1.24951100   -2.17749700    0.29344800
 H                 -1.32965400   -1.62829400   -0.65172300
 H                 -1.87518500   -1.67172300    1.03889900
 H                 -1.65962600   -3.18175600    0.13109400
 F                 -1.48196800   -0.46274700   -3.89241200




