%mem=15000MB
%nprocshared=7
#p opt freq b3lyp/TZVP scrf=(smd,solvent=1,4-dioxane) nosymm cphf=conver=7 empiricaldispersion=gd3 int=(acc2e=11,grid=ultrafine)

Title

0 1
 Cu                 3.86122747    0.53765526    5.39119412
 N                  4.85697898    2.75013205    7.01112393
 N                  5.90903992    0.93984484    7.46376808
 C                  4.92271733   -0.82748317    9.52718160
 H                  5.01543447    0.25572972    9.61591736
 C                  4.88968001    1.42744905    6.71098729
 C                  5.84173822    3.08615135    7.92751785
 H                  5.97147882    4.09288600    8.28260005
 C                  6.50776543    1.94321772    8.21201504
 H                  7.33627399    1.74703314    8.86893045
 C                  6.33453537   -0.43661323    7.43357176
 C                  5.88266276   -1.29862442    8.44464327
 C                  5.22907321   -1.41772276   10.90794458
 H                  4.57946106   -0.96221900   11.65898494
 H                  6.26524385   -1.23603345   11.20236578
 H                  5.05310368   -2.49481938   10.94180821
 C                  6.28321934   -2.63241711    8.37416651
 H                  5.94678956   -3.33357753    9.12615463
 C                  7.09709399   -3.08040697    7.34179370
 H                  7.39221095   -4.12210682    7.30297024
 C                  7.52767074   -2.20425401    6.35715679
 H                  8.15680972   -2.56975793    5.55560241
 C                  7.15462423   -0.85904192    6.37827059
 C                  7.62304242    0.07728488    5.27423423
 H                  7.23602199    1.07461821    5.48322193
 C                  7.06361498   -0.35063234    3.90958799
 H                  7.44339549   -1.33078856    3.61273547
 H                  7.35023079    0.36677301    3.13758394
 H                  5.97336257   -0.41075018    3.92290701
 C                  9.15398691    0.18420447    5.23649014
 H                  9.61818999   -0.77268509    4.98726081
 H                  9.55463836    0.50955388    6.19936643
 H                  9.46343395    0.90900327    4.47945106
 C                  3.94589849    3.67591964    6.38694697
 C                  4.32046565    4.25615109    5.16761021
 C                  3.40321892    5.11345129    4.55950348
 H                  3.64776610    5.56829461    3.60827613
 C                  2.17164358    5.36931818    5.14322007
 H                  1.46749281    6.02616548    4.64717705
 C                  1.82745923    4.77574153    6.35013647
 H                  0.85515304    4.97512275    6.78085875
 C                  2.70844677    3.91318393    7.00190775
 C                  2.30634498    3.20723585    8.28829875
 H                  3.21505856    2.84449201    8.77193094
 C                  1.60563743    4.13602708    9.28630076
 H                  2.20431650    5.02554477    9.49537758
 H                  1.43823180    3.61141099   10.22992322
 H                  0.63008077    4.46465753    8.92234210
 C                  1.43594269    1.98169002    7.96810958
 H                  0.50620563    2.28046198    7.47915989
 H                  1.18226905    1.43713758    8.88063506
 H                  1.95405025    1.29496803    7.29912900
 C                  5.64650568    3.94626684    4.48955477
 H                  6.24593551    3.34298324    5.17230844
 C                  6.44776004    5.22051494    4.18920874
 H                  5.94065045    5.85335241    3.45757325
 H                  7.42662524    4.96251879    3.77751819
 H                  6.60628685    5.81427270    5.09235796
 C                  5.43106392    3.11637862    3.21467739
 H                  4.90820710    2.18196854    3.42558530
 H                  6.39088925    2.86928694    2.75479156
 H                  4.83902076    3.66605052    2.47995419
 C                  3.47689323   -1.13130563    9.10339220
 H                  3.24586864   -0.67538670    8.14118115
 H                  2.76826922   -0.74715350    9.84095873
 H                  3.31940542   -2.20780381    9.00929157
 F                  3.04377975   -0.27095133    3.88398757
 B                  1.32257160   -0.44736927    3.62165336
 C                  0.96682873   -1.73114177    4.45838217
 C                  1.20725528   -0.65431506    2.06828893
 C                  0.70041844    0.92351437    4.06980208
 C                  0.52560520   -1.49752661    5.89696475
 H                  1.85148177   -2.38331209    4.42407400
 H                  0.19980229   -2.28568112    3.90040091
 H                  1.64429264   -1.60221161    1.73402419
 C                 -0.30967272   -0.69870257    1.72674795
 C                  1.99288078    0.49094991    1.37235848
 C                 -0.81481843    0.86580320    3.71687276
 H                  0.77218556    1.10700111    5.14670525
 C                  1.48613702    2.06035613    3.35719122
 H                 -0.38355557   -0.89924135    5.93889398
 H                  1.30371257   -1.00112993    6.47501868
 S                  0.16852968   -3.12721599    6.71101710
 H                 -0.71863152   -1.62670558    2.14436487
 H                 -0.44001997   -0.77646271    0.64148853
 C                 -1.13594010    0.48507347    2.26063558
 C                  1.62050326    1.91178981    1.83131117
 H                  1.87251441    0.41400891    0.28584564
 H                  3.05985521    0.32908237    1.56763861
 H                 -1.28170426    1.82791367    3.95584083
 H                 -1.28498145    0.13155541    4.38221346
 H                  2.49131565    2.09454087    3.79444855
 H                  1.02479123    3.02624118    3.59163442
 C                 -0.33909158   -2.50590444    8.34398164
 H                 -2.19892729    0.23515962    2.18760414
 H                 -0.99581622    1.35152494    1.61563851
 H                  2.38391745    2.61014715    1.47470595
 H                  0.69440211    2.22249181    1.34929126
 F                  0.62849758   -1.79684462    8.96835184
 F                 -1.42103921   -1.69574268    8.29114079
 F                 -0.65196651   -3.54825163    9.13522371


