%mem=13000MB
%nprocshared=6
#p opt freq b3lyp/TZVP scrf=(smd,solvent=1,4-dioxane) nosymm cphf=conver=7 empiricaldispersion=gd3 int=(acc2e=11,grid=ultrafine)

Title

0 1
 Cu                 3.71228600   -0.65783200    5.50762200
 N                  4.51661100    0.87266600    7.85750300
 N                  4.90493300   -1.21238900    8.15383100
 C                  2.63311000   -2.86076000    8.87631600
 H                  2.80649000   -1.81179000    9.11991000
 C                  4.39800400   -0.33711700    7.25031400
 C                  5.09451800    0.75470300    9.11199300
 H                  5.27455700    1.60906900    9.73982900
 C                  5.33603000   -0.56276400    9.30141100
 H                  5.76799700   -1.09548000   10.12961900
 C                  5.00090800   -2.63345300    7.93732800
 C                  3.92672600   -3.44340000    8.33024300
 C                  2.15506700   -3.55084100   10.15939700
 H                  1.26227300   -3.04993100   10.54098200
 H                  2.91937600   -3.52346700   10.93957900
 H                  1.88876300   -4.59555400    9.98593700
 C                  4.04970000   -4.81657800    8.11433100
 H                  3.23776500   -5.47528900    8.39381900
 C                  5.19008300   -5.34772900    7.52839200
 H                  5.26409800   -6.41648900    7.36656500
 C                  6.22940500   -4.51685500    7.13255300
 H                  7.10215600   -4.94544500    6.65726300
 C                  6.15791000   -3.13712200    7.32617300
 C                  7.26522200   -2.22563500    6.81896200
 H                  7.10608900   -1.23127300    7.23788900
 C                  7.18420100   -2.09724200    5.28934900
 H                  7.35583700   -3.06234600    4.80659300
 H                  7.93531300   -1.39530300    4.92017600
 H                  6.20236300   -1.73934500    4.97162000
 C                  8.66124000   -2.68268600    7.26004700
 H                  8.93667200   -3.64005800    6.81234800
 H                  8.72302200   -2.78907500    8.34532600
 H                  9.41042300   -1.95084500    6.94855600
 C                  4.12506800    2.10729300    7.22578000
 C                  5.00995800    2.69366500    6.31159900
 C                  4.57482400    3.84113000    5.64717100
 H                  5.22164100    4.31215700    4.91827100
 C                  3.31911800    4.37348400    5.89297300
 H                  2.99283100    5.25440400    5.35375900
 C                  2.47247900    3.78182400    6.82178400
 H                  1.49681700    4.21382500    6.99785300
 C                  2.85651200    2.63454000    7.51405000
 C                  1.91264800    1.94825900    8.49234100
 H                  2.52031300    1.41366300    9.22520100
 C                  1.03248200    2.93009400    9.27296600
 H                  1.62467100    3.71436900    9.74964400
 H                  0.48625800    2.39755200   10.05486100
 H                  0.28976200    3.40978600    8.63199100
 C                  1.04788700    0.90582200    7.76581500
 H                  0.41595000    1.38480900    7.01538900
 H                  0.40345600    0.37966000    8.47350200
 H                  1.66245300    0.16577100    7.25561900
 C                  6.39118900    2.12204000    6.02578500
 H                  6.55197600    1.27033500    6.68756700
 C                  7.49461100    3.14599100    6.32961100
 H                  7.43383200    4.01101400    5.66561500
 H                  8.47948900    2.69270800    6.19233900
 H                  7.42964100    3.50893300    7.35797300
 C                  6.50076500    1.60569000    4.58428700
 H                  5.76192500    0.82856400    4.38161800
 H                  7.49198400    1.18176200    4.40777200
 H                  6.34442300    2.40789200    3.86021100
 C                  1.55220500   -2.90796800    7.78607600
 H                  1.88981500   -2.41498800    6.87410300
 H                  0.63937300   -2.41286700    8.11871600
 H                  1.30129300   -3.93920100    7.53014900
 F                  3.06412300   -0.88715200    3.72705500
 B                  1.72468857   -0.53283079    2.84442580
 C                  1.28772412    0.94288626    3.34648718
 C                  2.22099254   -0.38059465    1.31863724
 H                  0.96143813    0.92348284    4.39731645
 C                  2.49569469    1.90249542    3.27444195
 C                  0.07884992    1.41186763    2.50945700
 C                  3.44895437    0.55593995    1.27037517
 H                  2.53404118   -1.34630963    0.89646852
 C                  1.03389269    0.12176140    0.45774280
 H                  3.20554652    1.59112915    4.04474481
 H                  2.19391603    2.92371147    3.54213355
 C                  3.23575183    1.93676106    1.92221363
 C                  0.30392205    1.37793928    0.98366089
 H                 -0.21667002    2.42990016    2.79852463
 H                 -0.77740029    0.77517524    2.75622477
 H                  3.78075779    0.70462807    0.23369514
 H                  4.27131162    0.05090913    1.78608130
 H                  0.30574456   -0.68927631    0.37386783
 H                  1.37050138    0.32202424   -0.56828557
 H                  4.21045497    2.41798542    2.06443607
 H                  2.69546209    2.58273774    1.22860388
 H                 -0.66421014    1.46194846    0.47714257
 H                  0.86047775    2.26807377    0.68891167
 C                  0.79511583   -1.79270529    3.28320649
 C                 -0.49355049   -2.15562715    2.51577761
 H                 -0.85213598   -1.30207199    1.93845966
 C                  1.68885280   -3.04683209    3.28363718
 C                  0.39291752   -1.58446552    4.75510076
 H                 -1.25948132   -2.46786848    3.19456721
 H                 -0.28887937   -2.93936634    1.81666202
 F                  1.39219032   -0.95599049    5.41006107
 F                  0.16049914   -2.78269059    5.33193555
 F                 -0.72651333   -0.83216764    4.81360256
 F                  2.67837033   -2.89393016    4.18916248
 F                  0.94715849   -4.12785585    3.60578184
 F                  2.22450030   -3.21810712    2.05634479


