%mem=32000MB
%nprocshared=14
#p opt freq b3lyp/TZVP scrf=(smd,solvent=1,4-dioxane) nosymm cphf=conver=7 empiricaldispersion=gd3 int=(acc2e=11,grid=ultrafine)

Title

0 1
 Cu                 3.40096270   -0.30001607    6.20578272
 N                  5.12214970    1.21712247    8.11041329
 N                  5.45634978   -0.89245079    8.30203506
 C                  4.39616694   -2.44788184   10.44166856
 H                  4.92010987   -1.53179637   10.63070991
 C                  4.72892137    0.02377145    7.62336854
 C                  6.18109985    1.03214417    9.06751529
 H                  6.73022580    1.80334307    9.53165387
 C                  6.31194522   -0.25862124    9.26665936
 H                  6.94819883   -0.73852685    9.97060584
 C                  5.45799673   -2.29100702    8.14416924
 C                  4.93367201   -3.09419176    9.12891211
 C                  4.59576013   -3.39519270   11.63793277
 H                  4.21160510   -2.93312466   12.52629199
 H                  5.63822596   -3.59581574   11.76555180
 H                  4.07387121   -4.30892546   11.45761067
 C                  4.86420063   -4.46110173    8.87159998
 H                  4.45594439   -5.11829605    9.60990977
 C                  5.30505773   -4.95344645    7.66258815
 H                  5.20422010   -5.99411004    7.45637180
 C                  5.87822581   -4.13706168    6.71809894
 H                  6.23674395   -4.53480841    5.79274007
 C                  6.01447200   -2.78514058    6.98995201
 C                  6.82386834   -1.80712864    6.07831871
 H                  6.58524712   -0.79549526    6.33946885
 C                  6.47034532   -2.02935355    4.61382920
 H                  6.67956024   -3.03835004    4.34501504
 H                  7.05047367   -1.36677768    4.00360363
 H                  5.43044510   -1.82485227    4.47212771
 C                  8.35318004   -2.06031758    6.27653366
 H                  8.58160832   -3.07260588    6.00860308
 H                  8.62500068   -1.89487418    7.29940582
 H                  8.91477794   -1.39313775    5.65109784
 C                  4.64343029    2.54306410    7.88142324
 C                  5.38040857    3.35439442    7.03815469
 C                  4.91254845    4.63466370    6.76157902
 H                  5.44712583    5.26095346    6.08021197
 C                  3.72854810    5.09124889    7.37793410
 H                  3.35764391    6.06740095    7.15006336
 C                  3.05441980    4.30339556    8.26577324
 H                  2.18600034    4.67677090    8.76649339
 C                  3.50274091    3.00846810    8.53010288
 C                  2.80253174    2.10938662    9.58698948
 H                  3.49084414    1.36225334    9.93355495
 C                  2.34537076    2.94781952   10.81618237
 H                  3.19881069    3.39887235   11.28335424
 H                  1.85515195    2.30517541   11.52299938
 H                  1.66801859    3.71048325   10.50123590
 C                  1.59405312    1.45369686    8.93919436
 H                  0.92657843    2.21504030    8.59626788
 H                  1.09436057    0.83428593    9.65283540
 H                  1.91453440    0.85814845    8.11209303
 C                  6.67610589    2.80049769    6.39706324
 H                  7.12860987    2.08899343    7.05912366
 C                  7.66931374    3.94361517    6.12453625
 H                  7.22300964    4.64974926    5.45707152
 H                  8.55858854    3.54482242    5.67919732
 H                  7.91903827    4.42865575    7.04393272
 C                  6.31188127    2.11382223    5.06605801
 H                  5.62951435    1.30939358    5.25235667
 H                  7.19662697    1.72799591    4.60433596
 H                  5.85188836    2.82737917    4.41534069
 C                  2.88279934   -2.16645441   10.27338455
 H                  2.72956514   -1.49553905    9.45194946
 H                  2.49404276   -1.72360085   11.16770765
 H                  2.37254450   -3.08691124   10.08045945
 F                  2.05074764   -0.62502481    4.76658551
 B                  1.08249049   -0.65406025    3.43087034
 C                  0.96340389    0.84032842    2.79094943
 C                  1.73465498   -1.61269784    2.28519440
 C                 -0.41018377   -1.21168352    3.85921579
 H                  0.53844815    1.50869496    3.51039282
 C                  2.36851123    1.32924111    2.39213642
 C                  0.06540344    0.78074178    1.54096450
 C                  3.12043002   -1.06229722    1.89905872
 H                  1.83325743   -2.60955032    2.66130965
 C                  0.81739110   -1.61101560    1.04784163
 C                 -0.28077054   -2.63341045    4.43674914
 C                 -1.02086505   -0.27948021    4.92207296
 H                 -1.04377288   -1.23317022    2.99723948
 H                  2.99615696    1.35249405    3.25840436
 H                  2.29462815    2.31266545    1.97702456
 C                  2.98204144    0.37519425    1.33547336
 C                  0.68604744   -0.17173330    0.48691977
 H                 -0.02004983    1.76138910    1.12152609
 H                 -0.90476680    0.42349466    1.81672562
 H                  3.55399563   -1.69285434    1.15118268
 H                  3.75056583   -1.04696416    2.76369376
 H                 -0.15022419   -1.97638895    1.32192732
 H                  1.23936929   -2.24429492    0.29565036
 C                 -1.67393319   -3.15385884    4.83653823
 H                  0.35281857   -2.61192375    5.29872545
 H                  0.14353398   -3.28111016    3.69827046
 C                 -2.41402770   -0.79992860    5.32186205
 H                 -0.38727594   -0.25799351    5.78404927
 H                 -1.11078204    0.70834304    4.52079979
 H                  3.95162374    0.73628493    1.06266633
 H                  2.34932633    0.35411673    0.47284521
 H                  0.05543056   -0.19182979   -0.37726683
 H                  1.65647962    0.18907572    0.21677491
 C                 -2.28461446   -2.22165552    5.89939540
 H                 -1.58401620   -4.14168209    5.23781140
 H                 -2.30752230   -3.17534553    3.97456192
 H                 -2.83833222   -0.15222889    6.06034073
 H                 -3.04761680   -0.82141529    4.45988574
 H                 -3.25259111   -2.58326576    6.17717094
 H                 -1.65102535   -2.20016882    6.76137171



