%mem=3200MB
%nprocshared=4
#p opt freq b3lyp/genecp 5d 7f empiricaldispersion=gd3
scf=(xqc,maxcyc=1000,conver=8,nosym)

of-vacuum-ligands

0 1
 C                  0.32136500    1.55202000    0.00009000
 C                  0.53784500    0.16848400   -0.00007900
 C                 -0.71202600    0.61293800    0.00001500
 C                  2.78800500   -0.28875900    0.00005700
 H                  2.96890800    0.31746700    0.89117400
 H                  3.43039000   -1.16747900    0.00020800
 H                  2.96915900    0.31737000   -0.89106900
 C                 -2.76231420    1.66925215   -0.00024779
 H                 -2.53677811    2.25823278    0.89363973
 H                 -2.53741173    2.25759133   -0.89471056
 H                 -3.81265180    1.38212734    0.00023325
 O                  1.43864000   -0.77964600   -0.00010300
 O                 -2.00905800    0.45533000   -0.00011900

-H -C -N -O -P -B -S -Al -Cl -F -He -Si 0
6-31+g*
****
-Pd -Os -Au -W -Fe -K -Ti -Cu -Co -Pt -Ag -Cr -V -Sc -Mn -Hf -Ir -I -Br -Ta -Zn -Zr -Mo -Re -Ru -Rh -Ru -Ni -Nb -Xe -Sn -In -Y -Ga -Hg 0
sdd
*******************

-Pd -Os -Au -W -Fe -K -Ti -Cu -Co -Pt -Ag -Cr -V -Sc -Mn -Hf -Ir -I -Br -Ta -Zn -Zr -Mo -Re -Ru -Rh -Ru -Ni -Nb -Xe -Sn -In -Y -Ga -Hg 0
sdd


