%mem=3200MB
%nprocshared=4
#p opt freq b3lyp/genecp 5d 7f empiricaldispersion=gd3
scf=(xqc,maxcyc=1000,conver=8,nosym)

of-vacuum-complexes

0 1
 Pd                -1.23235400   -0.20122100    0.00010600
 P                 -3.50150500   -0.23619600   -0.00018100
 H                 -4.22910200   -1.45603500    0.00003600
 H                 -4.23744900    0.36872600    1.05285400
 H                 -4.23704400    0.36812300   -1.05384500
 C                  0.77465900   -0.12375900    0.00013200
 C                  1.93607100    0.67558500    0.00001700
 C                  2.07410100   -0.66318600    0.00008400
 O                  2.44277500    1.89094400   -0.00012300
 O                  2.79015500   -1.76751900   -0.00001500
 C                  1.43985700    2.94712000   -0.00001200
 C                  2.02984179   -2.99895920   -0.00012598
 H                  0.81543400    2.86575400    0.89367600
 H                  2.00603400    3.87835300   -0.00002000
 H                  0.81531100    2.86581100   -0.89361900
 H                  1.40654443   -3.05692702    0.89815411
 H                  1.40658853   -3.05679620   -0.89844490
 H                  2.76910754   -3.80023191   -0.00016681

-H -C -N -O -P -B -S -Al -Cl -F -He -Si 0
6-31+g*
****
-Pd -Os -Au -W -Fe -K -Ti -Cu -Co -Pt -Ag -Cr -V -Sc -Mn -Hf -Ir -I -Br -Ta -Zn -Zr -Mo -Re -Ru -Rh -Ru -Ni -Nb -Xe -Sn -In -Y -Ga -Hg 0
sdd
*******************

-Pd -Os -Au -W -Fe -K -Ti -Cu -Co -Pt -Ag -Cr -V -Sc -Mn -Hf -Ir -I -Br -Ta -Zn -Zr -Mo -Re -Ru -Rh -Ru -Ni -Nb -Xe -Sn -In -Y -Ga -Hg 0
sdd


