%mem=3200MB
%nprocshared=4
#p opt freq b3lyp/genecp 5d 7f empiricaldispersion=gd3
scf=(xqc,maxcyc=1000,conver=8,nosym)

of-vacuum-complexes

1 1
 C                 -0.77899600   -0.00004100   -0.01045700
 C                 -1.98973800    0.00033700    0.69383000
 C                 -2.01376000   -0.00031800   -0.66656300
 C                 -1.80283800    0.00147300    3.03158100
 H                 -1.18312000    0.90162300    3.05074200
 H                 -2.50826600    0.00117300    3.86075600
 H                 -1.18205600   -0.89793900    3.05097500
 C                 -1.73692022   -0.00168556   -3.00445685
 H                 -1.11841484    0.89942103   -3.00501721
 H                 -1.11842354   -0.90279783   -3.00388512
 H                 -2.41712603   -0.00221742   -3.85450352
 O                 -2.63079000    0.00085800    1.82807800
 O                 -2.60287700   -0.00093600   -1.82496900
 Pd                 1.30386400   -0.00004900   -0.11418300
 P                  1.67191100    2.28674400   -0.17402000
 P                  1.67188900   -2.28692600   -0.17211000
 H                  2.30950400    2.77382800   -1.33060500
 H                  0.59432700    3.19285300   -0.09054300
 H                  2.51572800    2.82182100    0.81764200
 H                  2.30992100   -2.77495600   -1.32805000
 H                  2.51527200   -2.82127200    0.82031900
 H                  0.59420800   -3.19289200   -0.08834600
 H                  2.89094300   -0.00006100   -0.20361800

-H -C -N -O -P -B -S -Al -Cl -F -He -Si 0
6-31+g*
****
-Pd -Os -Au -W -Fe -K -Ti -Cu -Co -Pt -Ag -Cr -V -Sc -Mn -Hf -Ir -I -Br -Ta -Zn -Zr -Mo -Re -Ru -Rh -Ru -Ni -Nb -Xe -Sn -In -Y -Ga -Hg 0
sdd
*******************

-Pd -Os -Au -W -Fe -K -Ti -Cu -Co -Pt -Ag -Cr -V -Sc -Mn -Hf -Ir -I -Br -Ta -Zn -Zr -Mo -Re -Ru -Rh -Ru -Ni -Nb -Xe -Sn -In -Y -Ga -Hg 0
sdd


