%mem=3200MB
%nprocshared=4
#p opt freq b3lyp/genecp 5d 7f empiricaldispersion=gd3
scf=(xqc,maxcyc=1000,conver=8,nosym)

of-vacuum-complexes

0 1
 C                 -0.62548800    0.32005500    0.00017200
 C                 -1.77561500    1.08803500    0.00020100
 C                 -1.93173800   -0.25772500    0.00023600
 N                 -2.62875900   -1.38733700    0.00022100
 C                 -1.38147500    3.37601400    0.00029300
 H                 -0.75328700    3.32207400   -0.89391600
 H                 -1.97832300    4.28845600    0.00046200
 H                 -0.75309700    3.32186400    0.89435600
 C                 -4.08592300   -1.39581100    0.00009000
 H                 -4.46615200   -1.91263800    0.89118100
 H                 -4.45489900   -0.36771500    0.00051500
 H                 -4.46603000   -1.91185900   -0.89151000
 O                 -2.33965900    2.28713400    0.00026600
 C                 -1.93082000   -2.67071900   -0.00008200
 H                 -0.85323700   -2.48779400    0.00011200
 H                 -2.20110900   -3.24995000    0.89221900
 H                 -2.20086000   -3.24941500   -0.89281200
 Pd                 1.36746800   -0.01682300   -0.00002700
 P                  3.58666200   -0.43801500   -0.00047000
 H                  4.44452751    0.04088553   -1.02777815
 H                  4.41046339   -0.00962081    1.07521343
 H                  4.07600868   -1.77187459   -0.02560219

-H -C -N -O -P -B -S -Al -Cl -F -He -Si 0
6-31+g*
****
-Pd -Os -Au -W -Fe -K -Ti -Cu -Co -Pt -Ag -Cr -V -Sc -Mn -Hf -Ir -I -Br -Ta -Zn -Zr -Mo -Re -Ru -Rh -Ru -Ni -Nb -Xe -Sn -In -Y -Ga -Hg 0
sdd
*******************

-Pd -Os -Au -W -Fe -K -Ti -Cu -Co -Pt -Ag -Cr -V -Sc -Mn -Hf -Ir -I -Br -Ta -Zn -Zr -Mo -Re -Ru -Rh -Ru -Ni -Nb -Xe -Sn -In -Y -Ga -Hg 0
sdd


