%mem=3200MB
%nprocshared=4
#p opt freq b3lyp/genecp 5d 7f empiricaldispersion=gd3
scf=(xqc,maxcyc=1000,conver=8,nosym)

of-vacuum-complexes

0 1
 Pd                -0.18379431    0.52929059   -1.92121001
 P                 -2.37935331    0.52926459   -1.92122301
 H                 -3.10493333    1.74896812   -1.91979792
 H                 -3.10546233   -0.07903331   -2.97804951
 H                 -3.10547428   -0.08150803   -0.86583334
 C                  1.86620569    0.52931350   -1.92119787
 C                  3.08898627   -0.13251644   -1.92695831
 C                  3.12760397    1.21208174   -1.91524051
 O                  3.75607665   -1.28166727   -1.93363315
 N                  3.74810083    2.39273979   -1.92549488
 C                  2.90106893   -2.44989792   -1.93777661
 C                  5.19044038    2.55265857   -1.77241391
 H                  3.16047687    3.21453912   -1.84074224
 H                  2.26600590   -2.44940186   -2.82931213
 H                  3.57582876   -3.30665786   -1.94722540
 H                  2.27499317   -2.46224464   -1.03994172
 H                  5.47788890    2.70069629   -0.72285142
 H                  5.68601166    1.65372466   -2.14792657
 H                  5.53242589    3.41052492   -2.36019370

-H -C -N -O -P -B -S -Al -Cl -F -He -Si 0
6-31+g*
****
-Pd -Os -Au -W -Fe -K -Ti -Cu -Co -Pt -Ag -Cr -V -Sc -Mn -Hf -Ir -I -Br -Ta -Zn -Zr -Mo -Re -Ru -Rh -Ru -Ni -Nb -Xe -Sn -In -Y -Ga -Hg 0
sdd
*******************

-Pd -Os -Au -W -Fe -K -Ti -Cu -Co -Pt -Ag -Cr -V -Sc -Mn -Hf -Ir -I -Br -Ta -Zn -Zr -Mo -Re -Ru -Rh -Ru -Ni -Nb -Xe -Sn -In -Y -Ga -Hg 0
sdd

