%mem=3200MB
%nprocshared=4
#p opt guess=always freq b3lyp/genecp 5d 7f empiricaldispersion=gd3
scf=(xqc,maxcyc=1000,conver=8,nosym)

of-vacuum-complexes

0 1
 Pd                 0.60719640    0.81709144    0.00000000
 P                 -1.58836260    0.81706544   -0.00001300
 H                 -2.31394262    2.03676896    0.00141209
 H                 -2.31447162    0.20876754   -1.05683950
 H                 -2.31448357    0.20629282    1.05537667
 C                  2.65719640    0.81711435    0.00001214
 C                  3.89212613    0.84121934   -0.67826630
 C                  3.89211866    0.79303694    0.67830521
 N                  4.49418134    0.91927808   -1.88087731
 N                  4.49416245    0.71499115    1.88092338
 C                  3.66995837    0.74907829   -3.07366117
 C                  5.92135396    0.68281799   -2.02998256
 C                  5.92132583    0.95148726    2.03004444
 C                  3.66992042    0.88517485    3.07369741
 H                  2.63312019    0.98147406   -2.82232030
 H                  4.01330918    1.42799901   -3.86329027
 H                  3.72038257   -0.28410134   -3.45106157
 H                  6.44347796    0.99748093   -1.12369809
 H                  6.14376338   -0.38000572   -2.21856652
 H                  6.30619114    1.27031546   -2.87190491
 H                  6.30616865    0.36399972    2.87197232
 H                  6.44346883    0.63683646    1.12376815
 H                  6.14370741    2.01431710    2.21863001
 H                  3.72031723    1.91835660    3.45109638
 H                  2.63309060    0.65275510    2.82234527
 H                  4.01327761    0.20626413    3.86333252

-H -C -N -O -P -B -S -Al -Cl -F -He -Si 0
6-31+g*
****
-Pd -Os -Au -W -Fe -K -Ti -Cu -Co -Pt -Ag -Cr -V -Sc -Mn -Hf -Ir -I -Br -Ta -Zn -Zr -Mo -Re -Ru -Rh -Ru -Ni -Nb -Xe -Sn -In -Y -Ga -Hg 0
sdd
*******************

-Pd -Os -Au -W -Fe -K -Ti -Cu -Co -Pt -Ag -Cr -V -Sc -Mn -Hf -Ir -I -Br -Ta -Zn -Zr -Mo -Re -Ru -Rh -Ru -Ni -Nb -Xe -Sn -In -Y -Ga -Hg 0
sdd

