%mem=3200MB
%nprocshared=4
#p opt freq b3lyp/genecp 5d 7f empiricaldispersion=gd3
scf=(xqc,maxcyc=1000,conver=8,nosym)

of-vacuum-complexes

1 1
 Pd                 0.72713642    2.06146923    0.00000000
 P                  1.00067016   -0.26073552    0.22514779
 H                  1.24807207   -0.97885252   -0.96228911
 H                  2.05947225   -0.69986571    1.04016151
 H                 -0.08243388   -0.97907894    0.76274429
 P                  0.40385126    4.38270373    0.15970050
 H                  0.46588203    5.10683262   -1.04806425
 H                 -0.82759180    4.81848470    0.68103010
 H                  1.31431560    5.09768801    0.95844747
 H                 -0.78832512    1.86105675   -0.39951363
 C                  2.76041055    2.32280493   -0.00000000
 C                  3.91570622    3.14525234    0.00127105
 C                  4.08612909    1.81924537   -0.00127104
 C                  4.43280267    4.53320130    0.00354268
 C                  4.93759190    0.60729320   -0.00230258
 H                  4.08255244    5.04775504    0.90736652
 H                  5.52580671    4.58275246   -0.03468547
 H                  4.01610234    5.07899559   -0.85217984
 H                  4.75255967    0.03653007    0.91667896
 H                  4.65110049   -0.04071312   -0.83990603
 H                  6.00623142    0.83532222   -0.07021245

-H -C -N -O -P -B -S -Al -Cl -F -He -Si 0
6-31+g*
****
-Pd -Os -Au -W -Fe -K -Ti -Cu -Co -Pt -Ag -Cr -V -Sc -Mn -Hf -Ir -I -Br -Ta -Zn -Zr -Mo -Re -Ru -Rh -Ru -Ni -Nb -Xe -Sn -In -Y -Ga -Hg 0
sdd
*******************

-Pd -Os -Au -W -Fe -K -Ti -Cu -Co -Pt -Ag -Cr -V -Sc -Mn -Hf -Ir -I -Br -Ta -Zn -Zr -Mo -Re -Ru -Rh -Ru -Ni -Nb -Xe -Sn -In -Y -Ga -Hg 0
sdd

