%mem=3200MB
%nprocshared=4
#p opt freq b3lyp/genecp 5d 7f empiricaldispersion=gd3
scf=(xqc,maxcyc=1000,conver=8,nosym)

of-vacuum-complexes

1 1
 C                 -0.00090600    2.87110600   -0.66942400
 C                 -0.00090300    2.87110800    0.66942000
 C                 -0.00048200    1.63776800    0.00000000
 H                 -0.00110300    3.41688800    1.60510400
 H                 -0.00111000    3.41688300   -1.60510900
 Pd                 0.00014800   -0.44545300    0.00001100
 P                 -2.30163100   -0.78317600   -0.00001700
 P                  2.30210100   -0.78196200   -0.00001700
 H                 -2.87906838   -1.60498853   -0.98194180
 H                 -2.86020573   -1.35151507    1.16279028
 H                 -3.11186064    0.36361463   -0.12467726
 H                  2.87677945   -1.62522026   -0.96523728
 H                  3.11128262    0.36214927   -0.15291975
 H                  2.86480140   -1.32391966    1.17334833
 H                  0.00056600   -2.02063100    0.00007400

-H -C -N -O -P -B -S -Al -Cl -F -He -Si 0
6-31+g*
****
-Pd -Os -Au -W -Fe -K -Ti -Cu -Co -Pt -Ag -Cr -V -Sc -Mn -Hf -Ir -I -Br -Ta -Zn -Zr -Mo -Re -Ru -Rh -Ru -Ni -Nb -Xe -Sn -In -Y -Ga -Hg 0
sdd
*******************

-Pd -Os -Au -W -Fe -K -Ti -Cu -Co -Pt -Ag -Cr -V -Sc -Mn -Hf -Ir -I -Br -Ta -Zn -Zr -Mo -Re -Ru -Rh -Ru -Ni -Nb -Xe -Sn -In -Y -Ga -Hg 0
sdd


