%mem=10000MB
%nprocshared=12
#p opt freq b3lyp/genecp 5d 7f empiricaldispersion=gd3
scf=(xqc,maxcyc=1000,conver=8,nosym)

pf3-pdph3

0 1
 Pd                -0.47777600   -0.00040400   -0.04325400
 P                 -2.81136000    0.00039200    0.00918300
 H                 -3.48803697    0.97049989    0.78511978
 H                 -3.57361300    0.16044493   -1.17314849
 H                 -3.49577712   -1.13390922    0.50520110
 P                  1.70612335    0.05237412    0.31064304
 F                  2.60648795   -1.23475384   -0.09660917
 F                  2.59849077    1.19890128   -0.41208937
 H                  2.26793274    0.22164238    1.60251333

-H -C -N -O -P -B -S -Al -Cl -F -He -Si 0
6-31+g*
****
-Pd -Os -Au -W -Fe -K -Ti -Cu -Co -Pt -Ag -Cr -V -Sc -Mn -Hf -Ir -I -Br -Ta -Zn -Zr -Mo -Re -Ru -Rh -Ru -Ni -Nb -Xe -Sn -In -Y -Ga -Hg 0
sdd
*******************

-Pd -Os -Au -W -Fe -K -Ti -Cu -Co -Pt -Ag -Cr -V -Sc -Mn -Hf -Ir -I -Br -Ta -Zn -Zr -Mo -Re -Ru -Rh -Ru -Ni -Nb -Xe -Sn -In -Y -Ga -Hg 0
sdd



