%mem=10000MB
%nprocshared=12
#p opt freq b3lyp/genecp 5d 7f empiricaldispersion=gd3
scf=(xqc,maxcyc=1000,conver=8,nosym)

pf3-pdph3

0 1
 Pd                 0.30740288   -0.16616160   -0.02379148
 P                  2.58480100    0.01785000    0.00000100
 H                  3.29231945    1.06737391    0.63663159
 H                  3.22515506   -1.04896735    0.67429576
 H                  3.37744333   -0.02567243   -1.17354225
 P                 -1.91503281   -0.45709626   -0.05877169
 F                 -2.93289953    0.63371387    0.63129622
 H                 -2.58752644   -0.57000078   -1.30313787
 H                 -2.47843300   -1.62277508    0.52193130

-H -C -N -O -P -B -S -Al -Cl -F -He -Si 0
6-31+g*
****
-Pd -Os -Au -W -Fe -K -Ti -Cu -Co -Pt -Ag -Cr -V -Sc -Mn -Hf -Ir -I -Br -Ta -Zn -Zr -Mo -Re -Ru -Rh -Ru -Ni -Nb -Xe -Sn -In -Y -Ga -Hg 0
sdd
*******************

-Pd -Os -Au -W -Fe -K -Ti -Cu -Co -Pt -Ag -Cr -V -Sc -Mn -Hf -Ir -I -Br -Ta -Zn -Zr -Mo -Re -Ru -Rh -Ru -Ni -Nb -Xe -Sn -In -Y -Ga -Hg 0
sdd



