%mem=10000MB
%nprocshared=12
#p opt freq b3lyp/genecp 5d 7f empiricaldispersion=gd3
scf=(xqc,maxcyc=1000,conver=8,nosym)

pf3-pdph3

0 1
 Pd                -0.65655400   -0.00291900    0.00367700
 P                 -3.00131900    0.00305400   -0.00387900
 H                 -3.70633100    0.56175700    1.08697400
 H                 -3.69721300    0.67428700   -1.03549600
 H                 -3.70729600   -1.22009000   -0.07166600
 P                  1.53849400    0.00037800   -0.00066100
 F                  2.34477800    0.64101000    1.22980700
 F                  2.34600000   -1.38462000   -0.06656200
 F                  2.33752000    0.75103700   -1.17223000

-H -C -N -O -P -B -S -Al -Cl -F -He -Si 0
6-31+g*
****
-Pd -Os -Au -W -Fe -K -Ti -Cu -Co -Pt -Ag -Cr -V -Sc -Mn -Hf -Ir -I -Br -Ta -Zn -Zr -Mo -Re -Ru -Rh -Ru -Ni -Nb -Xe -Sn -In -Y -Ga -Hg 0
sdd
*******************

-Pd -Os -Au -W -Fe -K -Ti -Cu -Co -Pt -Ag -Cr -V -Sc -Mn -Hf -Ir -I -Br -Ta -Zn -Zr -Mo -Re -Ru -Rh -Ru -Ni -Nb -Xe -Sn -In -Y -Ga -Hg 0
sdd


