%mem=10000mb
%nproc=12
#p b3lyp/genecp 5d 7f empiricaldispersion=gd3
scf=(maxcyc=1000,conver=8,nosym) scrf=pcm

pf3-oso3_aq

2 1
 Os	 0.000015000	 0.000112000	 0.021906000
 O	 0.742525000	 1.467340000	 0.423647000
 O	 0.899915000	-1.376304000	 0.422695000
 O	-1.641674000	-0.090440000	 0.423944000
 P	-0.001405000	-0.000169000	-2.516467000
 F	 1.436661000	 0.079443000	-3.007814000
 F	-0.651658000	-1.285316000	-3.007460000
 F	-0.789831000	 1.205584000	-3.006714000

-H -C -N -O -P -B -S -Al -Cl -F -He -Si 0
6-31+g*
****
-Pd -Os -Au -W -Fe -K -Ti -Cu -Co -Pt -Ag -Cr -V -Sc -Mn -Hf -Ir -I -Br -Ta -Zn -Zr -Mo -Re -Ru -Rh -Ru -Ni -Nb -Xe -Sn -In -Y -Ga -Hg 0
sdd
*******************

-Pd -Os -Au -W -Fe -K -Ti -Cu -Co -Pt -Ag -Cr -V -Sc -Mn -Hf -Ir -I -Br -Ta -Zn -Zr -Mo -Re -Ru -Rh -Ru -Ni -Nb -Xe -Sn -In -Y -Ga -Hg 0
sdd


