%mem=10000MB
%nprocshared=12
#p opt freq b3lyp/genecp 5d 7f empiricaldispersion=gd3
scf=(xqc,maxcyc=1000,conver=8,nosym)

of-vacuum-pyc4-3-5-me2nh-oso32

2 1
 Os                -0.00013500    0.00000900   -0.16203300
 O                  0.82042620    1.61368520    0.47759850
 O                  0.98754871   -1.51720446    0.47745446
 O                 -1.80744221   -0.09649201    0.47884781
 C                 -0.00112642    0.00004947   -2.19203276
 C                 -1.07178455    0.54754300   -2.96465195
 C                  1.06878376   -0.54741692   -2.96572442
 C                 -1.06061973    0.54169898   -4.34960168
 C                  1.05639121   -0.54122938   -4.35066443
 H                 -1.84900755    0.94500462   -4.98074231
 N                 -0.00240552    0.00031660   -5.01142549
 H                  1.84429986   -0.94421414   -4.98261166
 H                 -0.00276189    0.00059821   -6.02357839
 H                  1.90730501   -0.97636022   -2.45799441
 H                 -1.90992034    0.97624123   -2.45607921

-H -C -N -O -P -B -S -Al -Cl -F -He -Si 0
6-31+g*
****
-Pd -Os -Au -W -Fe -K -Ti -Cu -Co -Pt -Ag -Cr -V -Sc -Mn -Hf -Ir -I -Br -Ta -Zn -Zr -Mo -Re -Ru -Rh -Ru -Ni -Nb -Xe -Sn -In -Y -Ga -Hg 0
sdd
*******************

-Pd -Os -Au -W -Fe -K -Ti -Cu -Co -Pt -Ag -Cr -V -Sc -Mn -Hf -Ir -I -Br -Ta -Zn -Zr -Mo -Re -Ru -Rh -Ru -Ni -Nb -Xe -Sn -In -Y -Ga -Hg 0
sdd



