%mem=3200MB
%nprocshared=4
#p opt freq b3lyp/genecp 5d 7f empiricaldispersion=gd3
scf=(xqc,maxcyc=1000,conver=8,nosym)

of-vacuum-complexes

1 1
 C                  0.00753400   -1.31529700   -0.00456100
 C                 -0.73888700    0.87279000    0.00472600
 N                  1.01948100   -0.43792300   -0.03049800
 N                  0.62740900    0.90897800    0.07557600
 C                 -1.14491100   -0.44224100   -0.01016500
 H                 -2.17368200   -0.77713200   -0.00765000
 H                 -1.29474500    1.80172600   -0.01020800
 H                  1.99888400   -0.64407400    0.11521600
 H                  1.19889900    1.63057700   -0.35290300
 Pd                 0.07534931   -3.36382599    0.03325541
 P                  0.08030036   -3.21277146   -2.31095131
 P                  0.05749767   -3.12710908    2.37030346
 H                  0.12409012   -4.43275522   -3.01566986
 H                 -1.02758869   -2.58656076   -2.90977227
 H                  1.14894571   -2.51379852   -2.90050671
 H                  0.09420494   -4.32048622    3.11957625
 H                  1.12047542   -2.40684479    2.94427147
 H                 -1.05605893   -2.47960721    2.93499591
 H                  0.12766792   -4.94269053    0.06240193

-H -C -N -O -P -B -S -Al -Cl -F -He -Si 0
6-31+g*
****
-Pd -Os -Au -W -Fe -K -Ti -Cu -Co -Pt -Ag -Cr -V -Sc -Mn -Hf -Ir -I -Br -Ta -Zn -Zr -Mo -Re -Ru -Rh -Ru -Ni -Nb -Xe -Sn -In -Y -Ga -Hg 0
sdd
*******************

-Pd -Os -Au -W -Fe -K -Ti -Cu -Co -Pt -Ag -Cr -V -Sc -Mn -Hf -Ir -I -Br -Ta -Zn -Zr -Mo -Re -Ru -Rh -Ru -Ni -Nb -Xe -Sn -In -Y -Ga -Hg 0
sdd


