%mem=3200MB
%nprocshared=4
#p opt freq b3lyp/genecp 5d 7f empiricaldispersion=gd3
scf=(xqc,maxcyc=1000,conver=8,nosym)

of-vacuum-ligands

0 1
 C                  0.49922000    0.00000038    0.00012869
 N                  1.36033507   -0.96205830    0.44952118
 C                  2.70892378   -0.61824122    0.28875162
 C                  2.70899821    0.61802985   -0.28838579
 N                  1.36044593    0.96205411   -0.44904058
 C                  0.90921874   -2.21316205    1.03437935
 H                  1.26843106   -3.06979819    0.45162130
 H                  1.26717770   -2.31477825    2.06589609
 H                 -0.18155777   -2.20506786    1.02975305
 C                  0.90948327    2.21322158   -1.03388335
 H                  1.26928094    3.06983057   -0.45145224
 H                  1.26697929    2.31452634   -2.06559418
 H                 -0.18129422    2.20551055   -1.02873690
 C                  3.83101199   -1.51161026    0.70604001
 H                  3.80309818   -1.72730581    1.78270138
 H                  3.80245573   -2.47613617    0.18128655
 H                  4.79662808   -1.04530813    0.48758385
 C                  3.83119700    1.51126225   -0.70566795
 H                  3.80322681    1.72707648   -1.78230456
 H                  3.80285126    2.47573748   -0.18081059
 H                  4.79675091    1.04477206   -0.48734182
 Pd                -1.55078000    0.00000000   -0.00013400
 P                 -3.74633900    0.00000000   -0.00041700
 H                 -4.47206200   -0.00013200    1.21920200
 H                 -4.47238300    1.05617400   -0.60992400
 H                 -4.47238200   -1.05604400   -0.61015100

-H -C -N -O -P -B -S -Al -Cl -F -He -Si 0
6-31+g*
****
-Pd -Os -Au -W -Fe -K -Ti -Cu -Co -Pt -Ag -Cr -V -Sc -Mn -Hf -Ir -I -Br -Ta -Zn -Zr -Mo -Re -Ru -Rh -Ru -Ni -Nb -Xe -Sn -In -Y -Ga -Hg 0
sdd
*******************

-Pd -Os -Au -W -Fe -K -Ti -Cu -Co -Pt -Ag -Cr -V -Sc -Mn -Hf -Ir -I -Br -Ta -Zn -Zr -Mo -Re -Ru -Rh -Ru -Ni -Nb -Xe -Sn -In -Y -Ga -Hg 0
sdd


