%mem=3200MB
%nprocshared=4
#p opt freq b3lyp/genecp 5d 7f empiricaldispersion=gd3
scf=(xqc,maxcyc=1000,conver=8,nosym)

of-vacuum-complexes

0 1
 C                 -0.00000200    0.36025600   -0.00001300
 N                 -1.06746400   -0.50180900    0.00943800
 C                 -0.67702000   -1.84546600    0.00540600
 C                  0.67702300   -1.84546200   -0.00540200
 N                  1.06746400   -0.50180800   -0.00944500
 H                 -1.37728000   -2.66572500    0.03567500
 H                  1.37728500   -2.66572100   -0.03565900
 C                 -2.42423800   -0.06009700    0.02392800
 C                 -3.41718400   -0.81268700   -0.61412700
 C                 -2.75744000    1.13231200    0.67784300
 C                 -4.74548000   -0.37913200   -0.58319000
 H                 -3.15504600   -1.71779800   -1.15397800
 C                 -4.08466300    1.56283700    0.69230400
 H                 -1.97233200    1.70609100    1.15744900
 C                 -5.08533700    0.80909600    0.06875300
 H                 -5.51072700   -0.96739600   -1.08285000
 H                 -4.33794300    2.48917700    1.20136200
 H                 -6.11815900    1.14634200    0.08850700
 C                  2.42423700   -0.06009400   -0.02392700
 C                  3.41718000   -0.81268800    0.61412400
 C                  2.75744200    1.13231600   -0.67784100
 C                  4.74547800   -0.37913600    0.58319000
 H                  3.15504000   -1.71780300    1.15396900
 C                  4.08466600    1.56283900   -0.69229800
 H                  1.97233500    1.70609700   -1.15744700
 C                  5.08533700    0.80909400   -0.06874700
 H                  5.51072300   -0.96740400    1.08284700
 H                  4.33794900    2.48917900   -1.20135300
 H                  6.11816000    1.14633900   -0.08850100
 Pd                -0.00000458    2.41025600   -0.00003561
 P                 -0.00000761    4.60581500   -0.00006127
 H                  0.22236026    5.33139489    1.19920160
 H                  0.92727586    5.33192950   -0.79192362
 H                 -1.14954224    5.33193061   -0.40683942

-H -C -N -O -P -B -S -Al -Cl -F -He -Si 0
6-31+g*
****
-Pd -Os -Au -W -Fe -K -Ti -Cu -Co -Pt -Ag -Cr -V -Sc -Mn -Hf -Ir -I -Br -Ta -Zn -Zr -Mo -Re -Ru -Rh -Ru -Ni -Nb -Xe -Sn -In -Y -Ga -Hg 0
sdd
*******************

-Pd -Os -Au -W -Fe -K -Ti -Cu -Co -Pt -Ag -Cr -V -Sc -Mn -Hf -Ir -I -Br -Ta -Zn -Zr -Mo -Re -Ru -Rh -Ru -Ni -Nb -Xe -Sn -In -Y -Ga -Hg 0
sdd

