%mem=3200MB
%nprocshared=4
#p opt freq b3lyp/genecp 5d 7f empiricaldispersion=gd3
scf=(xqc,maxcyc=1000,conver=8,nosym)

of-vacuum-complexes

0 1
 C                  1.27000800    0.08078600   -0.04017200
 C                  3.48774200    0.65875600    0.03584500
 N                  2.06539700   -1.01232900   -0.05103300
 N                  3.41550100   -0.70812200    0.10675000
 C                  2.21473800    1.16965400   -0.01636900
 H                  1.94559700    2.21555100   -0.01792400
 H                  4.45569200    1.14227200    0.04449800
 Pd                -0.77492700    0.02502100   -0.01290500
 P                 -3.03349400   -0.03194600    0.02553700
 H                 -3.80340700    1.16255400    0.04514300
 H                 -3.77141100   -0.65495400   -1.01687200
 H                 -3.73375000   -0.66534600    1.08736900
 C                  1.61944425   -2.38895159    0.20768770
 H                  1.10250825   -2.42642260    1.14378230
 H                  0.96213590   -2.70408739   -0.57559715
 H                  2.46908372   -3.03837576    0.24319839
 C                  4.40187951   -1.60137924   -0.51778898
 H                  5.34786087   -1.10451595   -0.57387929
 H                  4.50020791   -2.49037426    0.06950940
 H                  4.07554560   -1.85944130   -1.50359330

-H -C -N -O -P -B -S -Al -Cl -F -He -Si 0
6-31+g*
****
-Pd -Os -Au -W -Fe -K -Ti -Cu -Co -Pt -Ag -Cr -V -Sc -Mn -Hf -Ir -I -Br -Ta -Zn -Zr -Mo -Re -Ru -Rh -Ru -Ni -Nb -Xe -Sn -In -Y -Ga -Hg 0
sdd
*******************

-Pd -Os -Au -W -Fe -K -Ti -Cu -Co -Pt -Ag -Cr -V -Sc -Mn -Hf -Ir -I -Br -Ta -Zn -Zr -Mo -Re -Ru -Rh -Ru -Ni -Nb -Xe -Sn -In -Y -Ga -Hg 0
sdd

