%mem=3200MB
%nprocshared=4
#p opt freq b3lyp/genecp 5d 7f empiricaldispersion=gd3
scf=(xqc,maxcyc=1000,conver=8,nosym)

of-vacuum-complexes

1 1
 C                  0.76564500    0.00050700    0.45326700
 C                  2.77425300    0.00152300    1.49954200
 N                  1.77308300   -0.00029900   -0.45510100
 N                  3.00380300    0.00038600    0.16973400
 C                  1.40576000    0.00145500    1.71405300
 H                  0.91462400    0.00212200    2.67616500
 H                  3.60550300    0.00220300    2.19139300
 Pd                -1.29802100   -0.00004900   -0.00660300
 P                 -1.62286900    2.28671000   -0.02187400
 P                 -1.62213800   -2.28692800   -0.02011400
 H                 -2.22747700    2.85318200   -1.16080600
 H                 -2.47885000    2.78874300    0.97762600
 H                 -0.53292900    3.16938300    0.13439300
 H                 -2.22676200   -2.85446200   -1.15850900
 H                 -0.53190500   -3.16915400    0.13664200
 H                 -2.47778700   -2.78846600    0.97991800
 H                 -2.86738300   -0.00041600   -0.30663600
 C                  1.63006200   -0.00193000   -1.91067300
 H                  0.56923918   -0.02019413   -2.17087234
 H                  2.09307267    0.88692236   -2.34531997
 H                  2.11113807   -0.88884394   -2.32041642
 C                  4.28345800   -0.00003500   -0.52977900
 H                  4.39135300    0.89715500   -1.14610700
 H                  5.06715900    0.00059300    0.22900900
 H                  4.39148500   -0.89812900   -1.14476500

-H -C -N -O -P -B -S -Al -Cl -F -He -Si 0
6-31+g*
****
-Pd -Os -Au -W -Fe -K -Ti -Cu -Co -Pt -Ag -Cr -V -Sc -Mn -Hf -Ir -I -Br -Ta -Zn -Zr -Mo -Re -Ru -Rh -Ru -Ni -Nb -Xe -Sn -In -Y -Ga -Hg 0
sdd
*******************

-Pd -Os -Au -W -Fe -K -Ti -Cu -Co -Pt -Ag -Cr -V -Sc -Mn -Hf -Ir -I -Br -Ta -Zn -Zr -Mo -Re -Ru -Rh -Ru -Ni -Nb -Xe -Sn -In -Y -Ga -Hg 0
sdd


