%mem=3200MB
%nprocshared=4
#p opt freq b3lyp/genecp 5d 7f empiricaldispersion=gd3
scf=(xqc,maxcyc=1000,conver=8,nosym)

of-vacuum-ligands

0 1
 C                  0.00753400   -1.31529700   -0.00456100
 C                 -0.73888700    0.87279000    0.00472600
 N                  1.01948100   -0.43792300   -0.03049800
 N                  0.62740900    0.90897800    0.07557600
 C                 -1.14491100   -0.44224100   -0.01016500
 H                 -2.17368200   -0.77713200   -0.00765000
 H                 -1.29474500    1.80172600   -0.01020800
 C                  2.44295395   -0.73754468    0.18128401
 H                  3.03039144   -0.20374403   -0.53626324
 H                  2.72735954   -0.43845213    1.16848060
 H                  2.60724379   -1.78852980    0.06578885
 C                  1.45481308    1.95371012   -0.54477654
 H                  2.33659038    2.10562739    0.04198571
 H                  1.73171924    1.64969581   -1.53260157
 H                  0.89838946    2.86625815   -0.59526271

-H -C -N -O -P -B -S -Al -Cl -F -He -Si 0
6-31+g*
****
-Pd -Os -Au -W -Fe -K -Ti -Cu -Co -Pt -Ag -Cr -V -Sc -Mn -Hf -Ir -I -Br -Ta -Zn -Zr -Mo -Re -Ru -Rh -Ru -Ni -Nb -Xe -Sn -In -Y -Ga -Hg 0
sdd
*******************

-Pd -Os -Au -W -Fe -K -Ti -Cu -Co -Pt -Ag -Cr -V -Sc -Mn -Hf -Ir -I -Br -Ta -Zn -Zr -Mo -Re -Ru -Rh -Ru -Ni -Nb -Xe -Sn -In -Y -Ga -Hg 0
sdd

