%mem=3200MB
%nprocshared=4
#p opt=(maxstep=5,verytight) freq b3lyp/genecp 5d 7f empiricaldispersion=gd3
scf=(xqc,maxcyc=1000,conver=8,nosym)

of-vacuum-ligands

0 1
 C                  1.07357800   -0.00003100    0.00013700
 N                  1.92377800    1.07374600    0.00000000
 C                  3.25351600    0.67941200   -0.00037600
 C                  3.25337700   -0.67994200   -0.00054600
 N                  1.92351500   -1.07399200   -0.00027600
 H                  4.06947900    1.38686800   -0.00057800
 H                  4.06917700   -1.38758100   -0.00085400
 C                  1.48851500    2.46435300    0.00022000
 H                  1.85901900    2.97643400    0.89477500
 H                  1.85917200    2.97676700   -0.89407800
 H                  0.39662300    2.47256900    0.00012800
 C                  1.48817300   -2.46460200    0.00033700
 H                  1.86126500   -2.97794100   -0.89241300
 H                  1.85627500   -2.97576200    0.89641900
 H                  0.39628100   -2.47261900   -0.00261000
 Pd                -0.99895500    0.00034300    0.00025000
 P                 -3.24870200   -0.00022900   -0.00045900
 H                 -3.98476600   -0.62009200   -1.04643100
 H                 -3.98550100   -0.59764900    1.05798600
 H                 -3.98858200    1.21324600   -0.01366000

-H -C -N -O -P -B -S -Al -Cl -F -He -Si 0
6-31+g*
****
-Pd -Os -Au -W -Fe -K -Ti -Cu -Co -Pt -Ag -Cr -V -Sc -Mn -Hf -Ir -I -Br -Ta -Zn -Zr -Mo -Re -Ru -Rh -Ru -Ni -Nb -Xe -Sn -In -Y -Ga -Hg 0
sdd
*******************

-Pd -Os -Au -W -Fe -K -Ti -Cu -Co -Pt -Ag -Cr -V -Sc -Mn -Hf -Ir -I -Br -Ta -Zn -Zr -Mo -Re -Ru -Rh -Ru -Ni -Nb -Xe -Sn -In -Y -Ga -Hg 0
sdd

