%mem=3200MB
%nprocshared=4
#p opt freq b3lyp/genecp 5d 7f empiricaldispersion=gd3
scf=(xqc,maxcyc=1000,conver=8,nosym)

of-vacuum-ligands

1 1
 C                 -1.02919300   -0.02507800   -0.00016200
 N                 -1.86238000   -0.06629700    1.08161800
 C                 -3.19532700   -0.10382000    0.68425100
 C                 -3.19565800   -0.08557100   -0.68539800
 N                 -1.86290700   -0.03718200   -1.08225400
 H                 -4.00870200   -0.14039000    1.39358800
 H                 -4.00936900   -0.10335500   -1.39506900
 C                 -1.43471900   -0.06822900    2.48098700
 H                 -1.81819200    0.81949000    2.99225300
 H                 -1.80714600   -0.96484700    2.98448200
 H                 -0.34430300   -0.06203200    2.51570000
 C                 -1.43580600   -0.00540700   -2.48143100
 H                 -1.80927400   -0.88918400   -3.00638400
 H                 -1.81867000    0.89481500   -2.97084800
 H                 -0.34539700    0.00031200   -2.51645900
 Pd                 1.10407900    0.02650900    0.00029700
 P                  1.50113700   -2.25193900   -0.02054700
 P                  1.26849900    2.33903000    0.02083000
 H                  2.25083600   -2.75219400   -1.10230000
 H                  2.24753900   -2.77241800    1.05392500
 H                  0.42259400   -3.16108700   -0.03081100
 H                  2.52584500    2.96789400    0.03476300
 H                  0.66461000    3.02474400   -1.05353400
 H                  0.64904800    3.00779300    1.09700600
 H                  2.68965400    0.05765500    0.00074000

-H -C -N -O -P -B -S -Al -Cl -F -He -Si 0
6-31+g*
****
-Pd -Os -Au -W -Fe -K -Ti -Cu -Co -Pt -Ag -Cr -V -Sc -Mn -Hf -Ir -I -Br -Ta -Zn -Zr -Mo -Re -Ru -Rh -Ru -Ni -Nb -Xe -Sn -In -Y -Ga -Hg 0
sdd
*******************

-Pd -Os -Au -W -Fe -K -Ti -Cu -Co -Pt -Ag -Cr -V -Sc -Mn -Hf -Ir -I -Br -Ta -Zn -Zr -Mo -Re -Ru -Rh -Ru -Ni -Nb -Xe -Sn -In -Y -Ga -Hg 0
sdd


