%mem=3200mb
%nproc=4
#p B3LYP/genecp scf=(xqc,maxcyc=1000,conver=8)
opt freq 5D 7F scf=nosym empiricaldispersion=gd3

of-vacuum-ligands

2 1
 C                 -2.06228950    0.60606060    0.00000000
 N                 -3.12699150    1.46741660    0.00023900
 C                 -2.74205550    2.80470760    0.00032700
 C                 -1.38252450    2.80470760   -0.00028900
 N                 -0.99759050    1.46741660   -0.00034500
 H                 -3.44858050    3.62240260    0.00057000
 H                 -0.67600050    3.62240260   -0.00057400
 C                 -4.51218950    1.02340860   -0.00013600
 H                 -5.03494750    1.38857860    0.89139000
 H                 -5.03347350    1.38503160   -0.89398300
 H                 -4.51217650   -0.06744640    0.00199300
 C                  0.38760850    1.02340860    0.00019100
 H                  0.91084150    1.38981460   -0.89054500
 H                  0.90841350    1.38379160    0.89482000
 H                  0.38759750   -0.06744240   -0.00342800
 Os                -2.06228808   -1.42393940    0.00012491
 O                 -2.06366357   -2.06405078   -1.81002855
 O                 -3.62927265   -2.06388473    0.90645230
 O                 -0.49392668   -2.06388268    0.90406911

-H -C -N -O -P -B -S -Al -Cl -F -He -Si 0
6-31+g*
****
-Pd -Os -Au -W -Fe -K -Ti -Cu -Co -Pt -Ag -Cr -V -Sc -Mn -Hf -Ir -I -Br -Ta -Zn -Zr -Mo -Re -Ru -Rh -Ru -Ni -Nb -Xe -Sn -In -Y -Ga -Hg 0
sdd
*******************

-Pd -Os -Au -W -Fe -K -Ti -Cu -Co -Pt -Ag -Cr -V -Sc -Mn -Hf -Ir -I -Br -Ta -Zn -Zr -Mo -Re -Ru -Rh -Ru -Ni -Nb -Xe -Sn -In -Y -Ga -Hg 0
sdd

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