%mem=3200mb
%nproc=4
#p B3LYP/genecp scf=(xqc,maxcyc=1000,conver=8)
opt freq 5D 7F scf=nosym empiricaldispersion=gd3

of-vacuum-ligands

0 1
 C                 -0.00034000   -1.27908200   -0.00013100
 N                 -1.05209200   -0.40363400    0.00038300
 C                 -0.67924800    0.93952900   -0.00051000
 C                  0.67949400    0.93948500    0.00048800
 N                  1.05211100   -0.40404000   -0.00033600
 H                 -1.38631200    1.75552600   -0.00024700
 H                  1.38683000    1.75523800    0.00011800
 C                 -2.44409981   -0.87608946    0.00008585
 H                 -2.94513607   -0.51015483    0.87183955
 H                 -2.94277530   -0.51601149   -0.87545205
 H                 -2.45761780   -1.94599812    0.00365375
 C                  2.44398260   -0.87689499    0.00093567
 H                  2.94634755   -0.50929549   -0.86935168
 H                  2.94152953   -0.51877856    0.87791895
 H                  2.45720131   -1.94679777   -0.00483463

-H -C -N -O -P -B -S -Al -Cl -F -He -Si 0
6-31+g*
****
-Pd -Os -Au -W -Fe -K -Ti -Cu -Co -Pt -Ag -Cr -V -Sc -Mn -Hf -Ir -I -Br -Ta -Zn -Zr -Mo -Re -Ru -Rh -Ru -Ni -Nb -Xe -Sn -In -Y -Ga -Hg 0
sdd
*******************

-Pd -Os -Au -W -Fe -K -Ti -Cu -Co -Pt -Ag -Cr -V -Sc -Mn -Hf -Ir -I -Br -Ta -Zn -Zr -Mo -Re -Ru -Rh -Ru -Ni -Nb -Xe -Sn -In -Y -Ga -Hg 0
sdd


