%mem=10000mb
%nproc=12
#p b3lyp/genecp 5d 7f empiricaldispersion=gd3
scf=(maxcyc=1000,conver=8,nosym) scrf=pcm

imf2nme2-pdph3_aq

0 1
 Pd	 0.655633000	 0.044247000	-0.016242000
 P	-1.600397000	 0.087306000	-0.028498000
 H	-2.310790000	 1.315423000	-0.094687000
 H	-2.341982000	-0.561106000	-1.051709000
 H	-2.348236000	-0.451648000	 1.051981000
 C	 2.718497000	-0.003250000	 0.000005000
 N	 3.565154000	 0.295869000	 1.039919000
 N	 3.567180000	-0.344782000	-1.025072000
 C	 3.142590000	 0.719562000	 2.369995000
 C	 4.884347000	 0.142395000	 0.664685000
 C	 4.885609000	-0.258191000	-0.626528000
 C	 3.147012000	-0.748501000	-2.362072000
 H	 2.050951000	 0.750624000	 2.360663000
 H	 3.490467000	 0.005287000	 3.122403000
 H	 3.543698000	 1.712337000	 2.595407000
 F	 5.892357000	 0.375771000	 1.507436000
 F	 5.895242000	-0.542224000	-1.451595000
 H	 2.055371000	-0.718591000	-2.373735000
 H	 3.548628000	-0.057202000	-3.109139000
 H	 3.496073000	-1.762892000	-2.577682000

-H -C -N -O -P -B -S -Al -Cl -F -He -Si 0
6-31+g*
****
-Pd -Os -Au -W -Fe -K -Ti -Cu -Co -Pt -Ag -Cr -V -Sc -Mn -Hf -Ir -I -Br -Ta -Zn -Zr -Mo -Re -Ru -Rh -Ru -Ni -Nb -Xe -Sn -In -Y -Ga -Hg 0
sdd
*******************

-Pd -Os -Au -W -Fe -K -Ti -Cu -Co -Pt -Ag -Cr -V -Sc -Mn -Hf -Ir -I -Br -Ta -Zn -Zr -Mo -Re -Ru -Rh -Ru -Ni -Nb -Xe -Sn -In -Y -Ga -Hg 0
sdd


