%mem=40000MB
%nprocshared=20
#p opt=(calcfc,ts,noeigentest,maxstep=5) freq=noraman b3lyp/6-311+g(d)
scrf=(smd,solvent=water) nosymm empiricaldispersion=gd3

ch3nh3-sch3-ts_6311+Gd

0 1
 C                  0.01190400   -0.35798900    0.45609800
 H                  0.34329600   -0.62902900   -0.53098100
 H                  0.20204500    0.62961300    0.83834000
 H                 -0.42495700   -1.10459300    1.09733900
 N                 -1.78778600    0.20173800   -0.24635000
 S                  2.24673600   -0.96860400    1.24514300
 C                  3.02552900    0.29525800    0.14732900
 H                  2.72721600    0.09233700   -0.88719100
 H                  2.61980800    1.28023400    0.40321100
 C                  4.54792500    0.33114500    0.24081400
 H                  4.96151400    1.09594300   -0.42801900
 H                  4.87817500    0.56222400    1.25812800
 H                  4.98586300   -0.63140100   -0.04051400
 H                 -1.72143109    0.38109674   -1.22789341
 H                 -2.45064627   -0.52945117   -0.08517106
 H                 -2.08603868    1.03184982    0.22477599

