%mem=3000MB
%nprocshared=12
#p opt=(calcfc,ts,noeigentest,maxstep=5) freq b3lyp/6-311+g(d)
scrf=(smd,solvent=water) nosymm empiricaldispersion=gd3

ch3nh3-sh-ts_6311+Gd

0 1
 C                 -0.02378100   -0.03665800    0.14024000
 H                  0.16523700   -0.20890300   -0.90411000
 H                  0.03476800    0.95674300    0.54723900
 H                 -0.26815400   -0.86451100    0.78284000
 N                 -2.02682700    0.25227400   -0.26819300
 S                  2.31738500   -0.38066800    0.62796900
 H                  2.70285600    0.64874400   -0.16204500
 H                 -2.15236799    0.37156659   -1.25308322
 H                 -2.54808279   -0.54340872    0.04032184
 H                 -2.35022539    1.06861121    0.21035380

