%mem=16000MB
%nprocshared=12
#p opt=(calcfc,ts,noeigentest,maxstep=4) freq b3lyp/6-311+g(d)
scrf=(smd,solvent=water) nosymm empiricaldispersion=gd3

ch3nh3-ash2-ts_6311+Gd_ch2cl2_aq

0 1
 C                  0.21282600    0.03318800   -0.22845300
 H                  0.09885600   -0.87012500   -0.80306600
 H                  0.29368800    0.97838300   -0.73757200
 H                  0.04738400    0.01302700    0.83468800
 H                 -2.48108600    1.32941000    0.73172800
 H                 -2.69121300   -0.85605100    0.54116000
 N                  2.18900800   -0.18327000   -0.04811900
 As                -2.45819100    0.31683800   -0.42544500
 H                  2.63424338    0.70336156   -0.17321867
 H                  2.40376591   -0.53871540    0.86157194
 H                  2.51900464   -0.82289316   -0.74236998

