%mem=3000MB
%nprocshared=24
#p opt=(calcfc,ts,noeigentest,maxstep=4) freq=noraman b3lyp/6-311+g(d)
scrf=(smd,solvent=water) nosymm empiricaldispersion=gd3

ch3nh3-OTf-ts_6311+Gd_ch2cl2_aq

0 1
 C                  0.56391500   -0.71080500    0.12041900
 H                  0.50446800   -0.92255800   -0.93421600
 H                  0.84641400    0.28000600    0.43568600
 H                  0.06036300   -1.36530700    0.81245100
 S                  2.88133700   -1.71538500    1.60376700
 O                  3.95414300   -2.70207400    1.48773400
 O                  2.22153900   -1.46854400    0.24404800
 O                  1.91296000   -1.85620400    2.69299900
 C                  3.75446100   -0.07485500    1.93336800
 F                  4.42776500   -0.15016600    3.08395900
 F                  4.60765300    0.20234800    0.94583300
 F                  2.85321100    0.90875300    2.01945000
 H                 -1.54200800    0.96270800   -0.89737700
 H                 -2.26248900   -0.44412300   -0.44560700
 H                 -1.90159000    0.69476300    0.68403900
 N                 -1.57861300    0.25416700   -0.17157400

