%mem=40000MB
%nprocshared=20
#p opt=(calcfc,ts,noeigentest,maxstep=5) freq=noraman b3lyp/6-311+g(d)
scrf=(smd,solvent=water) nosymm empiricaldispersion=gd3

ch3cooh-oTs-ts_6311+Gd

-1 1
 C                  1.49046600    0.56325200    0.80585800
 H                  0.69412600    0.06141300    0.28619100
 H                  1.68200900    1.60292100    0.60763600
 H                  1.95814500    0.09246000    1.65258600
 C                  0.20890800   -3.23728000   -2.33088700
 C                  1.38492800   -2.53336200   -2.09590400
 C                  1.82863500   -2.37619400   -0.78250000
 C                  1.10992600   -2.90401400    0.28776800
 C                 -0.06602100   -3.60486600    0.03260200
 C                 -0.53353500   -3.78422000   -1.27452700
 H                 -0.13864200   -3.36372000   -3.35132200
 H                  1.94713300   -2.11625000   -2.92305400
 H                  1.45590800   -2.76855900    1.30465100
 H                 -0.62896600   -4.01410300    0.86515000
 C                 -1.78807700   -4.57010800   -1.54614100
 H                 -2.45952100   -4.56421200   -0.68496000
 H                 -2.32756800   -4.17548700   -2.41031000
 H                 -1.54523600   -5.61562200   -1.76552200
 S                  3.29471200   -1.39696500   -0.46481100
 O                  3.81798700   -1.79381700    0.86190800
 O                  2.81617700    0.07163400   -0.44680900
 O                  4.22454900   -1.57211500   -1.60180500
 O                  0.03075900    1.30618600    2.13593200
 O                 -0.57352300   -0.81118000    2.57350500
 C                 -0.69599700    0.42772200    2.72134900
 C                 -1.79408900    0.96949100    3.62353600
 H                 -1.47054300    1.87343200    4.14228700
 H                 -2.65602300    1.23397600    3.00227000
 H                 -2.11336200    0.21974900    4.34831900

