%mem=3000MB
%nprocshared=24
#p opt=(calcfc,ts,noeigentest,maxstep=4) freq b3lyp/6-311+g(d)
scrf=(smd,solvent=dichloromethane) nosymm empiricaldispersion=gd3

ch3cooch3-cooch3-ts_6311+Gd_aq_new

-1 1
 C                 -1.31677900   -0.09572700   -0.00614200
 H                 -0.99664200   -0.79397100   -0.75740600
 H                 -1.69409900   -0.45314200    0.93471900
 H                 -1.26414700    0.95882800   -0.20275500
 O                  0.47636000   -0.00373000    0.80508900
 C                  1.40172800   -0.73473200    0.29280600
 O                  1.27628700   -1.49175800   -0.68375400
 O                 -3.18914100   -0.19328900   -0.66111800
 O                 -2.67596600    1.22552400   -2.33023900
 C                 -3.46400100    0.48718100   -1.71660500
 C                 -4.89044500    0.30709600   -2.23487000
 H                 -4.92329800   -0.58572400   -2.86902600
 H                 -5.59878100    0.15777400   -1.41721500
 H                 -5.19593800    1.16313500   -2.83938100
 C                  2.76797600   -0.61210400    0.96535500
 H                  3.26286200   -1.58532700    0.99841100
 H                  3.39606500    0.05717200    0.36727700
 H                  2.69306000   -0.20000700    1.97287100

