%mem=3000MB %nprocshared=4 #p opt=(ts,calcfc,noeigentest,maxstep=8) freq=noraman b3lyp/6-311+G(d) scrf=(smd,solvent=dichloromethane) empiricaldispersion=gd3 nosymm ch3cooh-ph2-ts_6311+Gd_new -1 1 C 0.152833000 0.057834000 0.355132000 H 0.339329000 0.541968000 -0.587223000 H 0.265370000 0.626831000 1.261376000 H -0.442567000 -0.837646000 0.370942000 H -2.835657000 0.423776000 1.217012000 H -2.721366000 0.376346000 -0.856960000 P -2.316740000 1.268027000 0.185533000 O 1.811592000 -0.756088000 0.541058000 O 1.432699000 -1.901234000 -1.370553000 C 2.118852000 -1.592152000 -0.388908000 H 3.112484000 -2.054692000 -0.245512000