%mem=3000MB
%nprocshared=4
#p opt=(ts,calcfc,noeigentest,maxstep=8) freq=noraman b3lyp/6-311+G(d) scrf=(smd,solvent=dichloromethane) empiricaldispersion=gd3 nosymm

ch3cooh-sch3-ts_6311+Gd-1_new

-1 1
 O	 0.924844000	 2.076951000	 0.045896000
 O	 1.342730000	-0.139609000	-0.099985000
 C	 1.208380000	-0.275863000	 1.763171000
 H	 1.992995000	 0.424267000	 1.986605000
 H	 0.184331000	 0.045329000	 1.832702000
 H	 1.428634000	-1.327740000	 1.733981000
 S	 1.177417000	-0.623945000	 4.324064000
 C	 1.170792000	 1.039720000	-0.583762000
 H	 1.263107000	 1.077478000	-1.684881000
 C	 2.975070000	-1.033967000	 4.281106000
 H	 3.330554000	-1.337249000	 5.269697000
 H	 3.177619000	-1.856911000	 3.588067000
 H	 3.572795000	-0.174333000	 3.962011000




