%nprocshared=12
%mem=22GB
%chk=Int4D_to_Int5D_Htransf.chk
#p opt=(ts,calcfc,noeigentest,maxstep=5) freq wb97xd/6-311g(d,p) scrf=(smd,solvent=toluene)

TS Guess: H-transfer from Int4D, H atom set midway from two O atoms

-1 1
 H                  1.89649000    2.89517300   -2.30951600
 H                 -0.09393200    1.45784300   -2.07194200
 H                 -2.30342200    2.17291300   -0.07113600
 C                  1.62487000    2.50877500   -1.33230800
 C                  0.50826900    1.69469600   -1.20080300
 C                 -2.44646700    1.08659000   -0.06386500
 H                 -0.55755800   -0.78620400   -1.60677900
 C                 -2.78960200    0.55601100    1.34250500
 C                 -1.06420700   -1.01553700   -0.64109500
 C                  2.39341700    2.83008400   -0.21745700
 C                  0.13997500    1.18384400    0.04644800
 C                 -1.08947600    0.32950200    0.16905000
 H                  3.26917800    3.46241500   -0.32048900
 O                 -2.30400500   -1.54788200   -0.76936000
 H                 -3.08545900    1.29117000    2.10145800
 C                 -0.24258100   -2.09212300    0.08123100
 H                 -0.46198200   -3.04509300   -0.39080100
 C                  2.02511900    2.33654200    1.02863000
 C                  0.90509500    1.52427400    1.15946900
 O                 -1.44830200    0.08811700    1.55103400
 H                 -3.00167288   -0.56778634   -1.14762899
 H                 -0.49190700   -2.11753200    1.13973700
 H                  2.61502000    2.58296600    1.90596900
 H                  0.61103600    1.13649700    2.12694800
 H                 -3.50216600   -0.27298900    1.30746000
 O                 -3.21944000    0.71380900   -1.13809600
 Br                 1.74683100   -1.94753500   -0.00127800

