%nprocshared=4
%mem=7GB
#p B3LYP gen pseudo=read empiricaldispersion=GD3 nosymm scf=xqc SCRF=(SMD,solvent=dichloromethane) int=grid=ultrafine

Me2PhSi_SP

0 2
 Si	-0.459585000	-4.106749000	-1.506645000
 C	-0.922826000	-2.838404000	-2.835610000
 C	-1.656160000	-5.575966000	-1.493981000
 C	 1.316540000	-4.686023000	-1.710188000
 H	-1.969366000	-2.533057000	-2.726720000
 H	-0.306375000	-1.935407000	-2.776951000
 H	-0.799376000	-3.265871000	-3.839969000
 H	-1.456849000	-6.260756000	-0.663269000
 H	-2.690769000	-5.228695000	-1.398329000
 H	-1.576539000	-6.146962000	-2.428922000
 C	 2.292817000	-3.862560000	-2.311967000
 C	 1.730680000	-5.950988000	-1.238956000
 C	 3.615730000	-4.286235000	-2.446782000
 H	 2.016538000	-2.880213000	-2.687876000
 C	 3.053020000	-6.376883000	-1.371574000
 H	 1.010312000	-6.616449000	-0.768766000
 C	 4.000793000	-5.545546000	-1.976625000
 H	 4.346399000	-3.635990000	-2.921003000
 H	 3.344934000	-7.358255000	-1.006563000
 H	 5.030710000	-5.875971000	-2.080574000

-C -N -H -B -O -S -Br -Si 0
def2TZVP
****
-Cu 0
def2QZVP
****

-Cu 0
def2

