%nprocshared=24
%mem=90GB
#p opt freq b3lyp/genecp EmpiricalDispersion=GD3 scrf=(smd,solvent=toluene) 

TS FG8

0 1
 Ru                -0.31990400    0.28036100    0.33275700
 C                 -0.34164200   -1.75096900   -0.07429700
 N                 -1.43022300   -2.47887700   -0.38955600
 N                  0.72185000   -2.57150800   -0.00459000
 C                 -1.14466600   -3.93007400   -0.43497400
 H                 -1.54270800   -4.36704600   -1.35341500
 H                 -1.61780900   -4.42507100    0.42023800
 C                  0.38699800   -3.96589900   -0.36529900
 H                  0.85151000   -4.21847400   -1.32514200
 H                  0.76481900   -4.65180000    0.39649800
 Cl                -0.15167000   -0.24058800    2.72294500
 Cl                -0.32471000    0.81243100   -2.04041000
 C                 -1.90449600    1.24600900    0.69633800
 H                 -2.28397300    1.13927300    1.71822400
 C                 -2.95543500    1.64141100   -0.31162600
 H                 -3.26896900    0.69787500   -0.77075400
 C                 -0.84575100    3.82833900    0.36342700
 H                  0.05671600    4.38780100    0.11213300
 C                 -0.40968500    2.52380800    1.03583600
 H                 -0.58235500    2.51227800    2.11150300
 C                  0.90097700    1.91685000    0.74617500
 H                  1.47325400    1.61443100    1.62291700
 C                 -4.20560700    2.32705900    0.26487900
 H                 -5.00935400    2.21638600   -0.47555300
 H                 -4.53825500    1.77515700    1.15634300
 C                 -4.06513000    3.81642800    0.61173300
 H                 -3.78650300    4.37183800   -0.29548400
 H                 -5.06023400    4.18455300    0.89347600
 C                 -3.06597000    4.14252900    1.74592200
 H                 -2.90896100    3.25334500    2.37118900
 H                 -3.51123400    4.89032800    2.41469000
 C                 -1.71399400    4.70482100    1.28043700
 H                 -1.89559000    5.65100200    0.75156400
 H                 -1.12059200    4.96390400    2.16928900
 H                 -2.52788300    2.21472300   -1.13718800
 H                 -1.33275800    3.64178400   -0.59609200
 C                 -2.76886400   -2.00058000   -0.58617500
 C                 -3.62257900   -1.84670900    0.52069300
 C                 -3.21333000   -1.76411700   -1.90036500
 C                 -4.92222400   -1.38154300    0.28903300
 C                 -4.52247300   -1.30449600   -2.07946100
 C                 -5.38772200   -1.09772400   -0.99887200
 H                 -5.58634500   -1.23980300    1.13870600
 H                 -4.87071700   -1.09631200   -3.08865900
 C                  2.07799200   -2.22501900    0.31995200
 C                  2.93422400   -1.75672600   -0.69383100
 C                  2.54942600   -2.47916300    1.62255400
 C                  4.26666400   -1.49202000   -0.35905200
 C                  3.88255200   -2.17341300    1.91148200
 C                  4.75337900   -1.67176600    0.93859600
 H                  4.94228800   -1.13868900   -1.13449900
 H                  4.25262300   -2.34862400    2.91957100
 C                 -2.30775500   -1.99287500   -3.08362300
 H                 -2.02875000   -3.05039500   -3.17842400
 H                 -2.80279200   -1.69796300   -4.01399800
 H                 -1.38767600   -1.40943000   -2.98881500
 C                 -3.16306500   -2.17493600    1.91841500
 H                 -2.84516800   -3.22231700    1.99832700
 H                 -2.31189900   -1.55950200    2.22443200
 H                 -3.97215000   -2.01977700    2.63913000
 C                 -6.79614100   -0.60124100   -1.22251600
 H                 -6.84424800    0.09850800   -2.06429700
 H                 -7.47685800   -1.43240000   -1.45208900
 H                 -7.18782500   -0.09295100   -0.33498900
 C                  2.44753600   -1.53884600   -2.10341700
 H                  1.78003200   -2.34034800   -2.43867400
 H                  1.88119700   -0.60496900   -2.18451200
 H                  3.29039900   -1.49000100   -2.80054300
 C                  1.68582400   -3.13481600    2.67144800
 H                  0.62801600   -2.91195200    2.53044600
 H                  1.81935500   -4.22614100    2.64868000
 H                  1.96406000   -2.79339000    3.67304200
 C                  6.18135900   -1.32435500    1.28542200
 H                  6.58713000   -1.99899400    2.04784500
 H                  6.83307700   -1.37461900    0.40612100
 H                  6.25025300   -0.30473300    1.68799000
 C                  1.81477000    2.38860800   -0.34944600
 O                  2.83758300    1.50880300   -0.46450100
 O                  1.73280100    3.41671400   -0.98990000
 C                  3.87383100    1.78397500   -1.42606000
 H                  3.54759800    2.57633300   -2.10314500
 H                  4.00681800    0.86126800   -1.99351100
 C                  5.15792300    2.16090100   -0.68474300
 C                  6.30911800    2.33829200   -1.63586800
 C                  7.40541100    1.57781700   -1.64973100
 H                  6.20524200    3.14015000   -2.36880800
 H                  8.20703000    1.73897300   -2.36679600
 H                  7.54821300    0.76954900   -0.93388400
 H                  4.97130000    3.09164000   -0.13058600
 H                  5.38171600    1.37857600    0.04942200

-O -N -C -H -Cl 0
cc-pvTZ
****
Ru     0
S    9   1.00
    208.2500000              0.0005230
     18.8471000             -0.0449130
     11.7818000              0.2576260
      7.3619500             -0.2091300
      4.2777100             -0.5106620
      1.1910700              0.8032470
      0.5485680              0.4984140
      0.1386940              0.0337660
      0.0676510             -0.0120940
S    9   1.00
    208.2500000             -0.0001750
     18.8471000              0.0148030
     11.7818000             -0.0875270
      7.3619500              0.0842820
      4.2777100              0.1549110
      1.1910700             -0.3381410
      0.5485680             -0.3160050
      0.1386940              0.2835260
      0.0676510              0.6092730
S    9   1.00
    208.2500000             -0.0001820
     18.8471000              0.0052730
     11.7818000             -0.0785570
      7.3619500             -0.0138970
      4.2777100              0.5479870
      1.1910700             -1.4980850
      0.5485680              0.4795000
      0.1386940              2.1402540
      0.0676510             -1.4545610
S    9   1.00
    208.2500000             -0.0006350
     18.8471000              0.0517470
     11.7818000             -0.3171890
      7.3619500              0.3298480
      4.2777100              0.6270530
      1.1910700             -3.4222090
      0.5485680              3.8479480
      0.1386940             -1.6239260
      0.0676510             -0.6032230
S    1   1.00
      0.0301410              1.0000000
P    8   1.00
     22.7753000             -0.0015440
     14.2340000              0.0257710
      5.9875500             -0.1865980
      1.6392400              0.4427740
      0.8278800              0.4781510
      0.4090100              0.2083690
      0.1718770              0.0246350
      0.0712710             -0.0002190
P    8   1.00
     22.7753000             -0.0001480
     14.2340000             -0.0091740
      5.9875500              0.0813740
      1.6392400             -0.2361250
      0.8278800             -0.2943330
      0.4090100              0.0150980
      0.1718770              0.6560890
      0.0712710              0.4389440
P    8   1.00
     22.7753000             -0.0000630
     14.2340000             -0.0114610
      5.9875500              0.0999930
      1.6392400             -0.3036410
      0.8278800             -0.3638860
      0.4090100              0.1659350
      0.1718770              0.7005450
      0.0712710              0.3189430
P    8   1.00
     22.7753000              0.0011030
     14.2340000             -0.0225190
      5.9875500              0.1821610
      1.6392400             -0.7313300
      0.8278800             -0.4901170
      0.4090100              1.5235390
      0.1718770             -0.0391820
      0.0712710             -0.8661830
P    1   1.00
      0.0292260              1.0000000
D    7   1.00
     25.8838000              0.0015230
      7.5925500             -0.0181620
      2.7129300              0.1096910
      1.3970800              0.2915970
      0.6825650              0.3620440
      0.3193780              0.2975140
      0.1417810              0.1610370
D    7   1.00
     25.8838000             -0.0015510
      7.5925500              0.0190350
      2.7129300             -0.1257740
      1.3970800             -0.3632850
      0.6825650             -0.2793510
      0.3193780              0.2457120
      0.1417810              0.5472610
D    7   1.00
     25.8838000              0.0026560
      7.5925500             -0.0337600
      2.7129300              0.2929230
      1.3970800              0.6173710
      0.6825650             -0.3625300
      0.3193780             -0.8031580
      0.1417810              0.3154610
D    1   1.00
      0.0580170              1.0000000
F    1   1.00
      1.6965000              1.0000000
F    1   1.00
      0.4754000              1.0000000
G    1   1.00
      1.0311000              1.0000000
****

RU     0
RU-ECP     4     28
g potential
  1
2      1.0000000              0.0000000
s-g potential
  2
2     11.50059000           209.78649300
2      5.06857500            30.21430700
p-g potential
  4
2     10.53263400            48.75124400
2     10.19201000            97.49652900
2      4.73489200             7.86018800
2      4.50906500            15.32975100
d-g potential
  4
2      8.87797700            26.96750600
2      8.76612200            40.43230300
2      3.17019600             3.34075800
2      3.22885100             5.25635200
f-g potential
  2
2      7.82024900            -8.84752500
2      7.83964700           -11.83551800




